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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F09%3A00035344%21RIV10-MSM-14310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
The electrode processes of chlorobenzene (CB) and fluorobenzene (FB) on polycrystalline platinum (Pt pc) electrode in sulfuric acid were studied by differential electrochemical mass spectrometry (DEMS). Contrary to the oxidation of adsorbed benzene on Pt surface, the oxidation of adsorbed CB and FB in the oxygen adsorption region does not provide solely CO2 as the final product. At negative polarization potentials CB and FB were desorbed under dehalogenation. While in the case of FB only benzene was detected, CB gave intermediates besides benzene. The final product of stepwise hydrogenation of these species was cyclohexane. The electrode processes of chlorobenzene (CB) and fluorobenzene (FB) on polycrystalline platinum (Pt pc) electrode in sulfuric acid were studied by differential electrochemical mass spectrometry (DEMS). Contrary to the oxidation of adsorbed benzene on Pt surface, the oxidation of adsorbed CB and FB in the oxygen adsorption region does not provide solely CO2 as the final product. At negative polarization potentials CB and FB were desorbed under dehalogenation. While in the case of FB only benzene was detected, CB gave intermediates besides benzene. The final product of stepwise hydrogenation of these species was cyclohexane.
dcterms:title
ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE
skos:prefLabel
ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE
skos:notation
RIV/00216224:14310/09:00035344!RIV10-MSM-14310___
n4:aktivita
n7:Z n7:P
n4:aktivity
P(OC 174), Z(AV0Z40500505), Z(MSM0021622412)
n4:cisloPeriodika
4
n4:dodaniDat
n11:2010
n4:domaciTvurceVysledku
n5:9951636 n5:4370392 n5:3790185
n4:druhVysledku
n10:J
n4:duvernostUdaju
n8:S
n4:entitaPredkladatele
n12:predkladatel
n4:idSjednocenehoVysledku
312816
n4:idVysledku
RIV/00216224:14310/09:00035344
n4:jazykVysledku
n15:eng
n4:klicovaSlova
Electrochemical degradation; Hydrogenation; Dehalogenation; Fluorobenzene; Chlorobenzene; Differential electrochemical mass spectrometry (DEMS); Cyclic voltammetry (CV)
n4:klicoveSlovo
n6:Cyclic%20voltammetry%20%28CV%29 n6:Dehalogenation n6:Differential%20electrochemical%20mass%20spectrometry%20%28DEMS%29 n6:Chlorobenzene n6:Electrochemical%20degradation n6:Fluorobenzene n6:Hydrogenation
n4:kodStatuVydavatele
CZ - Česká republika
n4:kontrolniKodProRIV
[71F3D59734FB]
n4:nazevZdroje
Collect. Czech. Chem. Commun.
n4:obor
n9:CF
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
3
n4:projekt
n17:OC%20174
n4:rokUplatneniVysledku
n11:2009
n4:svazekPeriodika
74
n4:tvurceVysledku
Trnková, Libuše Janderka, Pavel Kebrlová, Natálie
n4:zamer
n16:AV0Z40500505 n16:MSM0021622412
s:issn
0010-0765
s:numberOfPages
14
n18:organizacniJednotka
14310