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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F08%3A00027896%21RIV10-MSM-14310___
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitate enantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It was evident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced). Enantiomeric fractions (EF) of PCB 95, 132, 149, and 174, alpha-HCH, o,p'-DDD, and o,p'-DDT were analyzed in 112 soil samples using two-dimensional gas chromatography and triple-quadrupole mass spectrometry. To assess the soil conditions that facilitate enantioselective fractionation of chiral compounds, EF values of selected PCBs were further correlated with a wide range of physicochemical and microbial soil parameters in an attempt to identify the influential factors and their mutual relations. It was evident that soils where nonracemic ratios of investigated compounds were found were more carbon rich but they also contained significantly more humic and fulvic acids and total nitrogen. These specific physicochemical properties were accompanied by significantly increased values of all key biotic variables, the amount of microbial biomass, and its respiration activity (both basal and substrate-induced).
dcterms:title
WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM? WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
skos:prefLabel
WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM? WHICH FACTORS AFFECT THE FATE OF CHIRAL PERSISTENT ORGANIC POLLUTANTS IN THE TERRESTRIAL ECOSYSTEM?
skos:notation
RIV/00216224:14310/08:00027896!RIV10-MSM-14310___
n4:aktivita
n8:Z
n4:aktivity
Z(MSM0021622412)
n4:cisloPeriodika
1
n4:dodaniDat
n16:2010
n4:domaciTvurceVysledku
n11:4561058 n11:3635872 n11:1204424 n11:4504135
n4:druhVysledku
n14:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
405725
n4:idVysledku
RIV/00216224:14310/08:00027896
n4:jazykVysledku
n18:eng
n4:klicovaSlova
Chiral analysis; degradation; enentiomer; GC MS
n4:klicoveSlovo
n6:GC%20MS n6:degradation n6:enentiomer n6:Chiral%20analysis
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[849F34750200]
n4:nazevZdroje
Organohalogen Compounds
n4:obor
n5:DK
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
5
n4:rokUplatneniVysledku
n16:2008
n4:svazekPeriodika
2008
n4:tvurceVysledku
Kobližková, Martina Klánová, Jana Dušek, Ladislav Bucheli, Thomas Hofman, Jakub
n4:zamer
n13:MSM0021622412
s:issn
1026-4892
s:numberOfPages
200
n9:organizacniJednotka
14310