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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F08%3A00026161%21RIV10-MSM-14310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process. The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process.
dcterms:title
Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2)
skos:prefLabel
Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2)
skos:notation
RIV/00216224:14310/08:00026161!RIV10-MSM-14310___
n3:aktivita
n14:Z
n3:aktivity
Z(MSM0021622415)
n3:cisloPeriodika
2
n3:dodaniDat
n9:2010
n3:domaciTvurceVysledku
n13:8675058
n3:druhVysledku
n4:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
398818
n3:idVysledku
RIV/00216224:14310/08:00026161
n3:jazykVysledku
n12:eng
n3:klicovaSlova
peroxovanadium complexes; ammine complexes; X-ray structure; IR spectra; thermal decomposition
n3:klicoveSlovo
n5:thermal%20decomposition n5:ammine%20complexes n5:X-ray%20structure n5:peroxovanadium%20complexes n5:IR%20spectra
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[B9F90B420A86]
n3:nazevZdroje
Polyhedron
n3:obor
n18:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n9:2008
n3:svazekPeriodika
27
n3:tvurceVysledku
Dudášová, D. Chrappová, J. Schwendt, P. Tatiersky, J. Marek, Jaromír
n3:wos
000253518700021
n3:zamer
n16:MSM0021622415
s:issn
0277-5387
s:numberOfPages
7
n15:organizacniJednotka
14310