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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F08%3A00025750%21RIV10-MSM-14310___
rdf:type
n4:Vysledek skos:Concept
dcterms:description
Dititanate [{Ti(C5Me4Et)(O2P(OH)Me)(O2P(O)Me)}2] (1) was prepared from (C5Me4Et)TiF3 and MeP(O)(OSiMe3)2. The molecular structure of the compound 1 has been determined by single-crystal X-ray diffraction analysis. In the cage cluster, two titanium atoms are bridged by two bidentate monoanionic and by two bidentate dianionic methylphosphonate groups. The OH groups of the monoanionic phosphonates and oxygen atoms of the dianionic phosphonates are connected by strong intramolecular hydrogen bonds. The NMR spectroscopy reveals the fast proton migration within the hydrogen bond. Dititanate [{Ti(C5Me4Et)(O2P(OH)Me)(O2P(O)Me)}2] (1) was prepared from (C5Me4Et)TiF3 and MeP(O)(OSiMe3)2. The molecular structure of the compound 1 has been determined by single-crystal X-ray diffraction analysis. In the cage cluster, two titanium atoms are bridged by two bidentate monoanionic and by two bidentate dianionic methylphosphonate groups. The OH groups of the monoanionic phosphonates and oxygen atoms of the dianionic phosphonates are connected by strong intramolecular hydrogen bonds. The NMR spectroscopy reveals the fast proton migration within the hydrogen bond.
dcterms:title
Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate
skos:prefLabel
Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate
skos:notation
RIV/00216224:14310/08:00025750!RIV10-MSM-14310___
n5:aktivita
n8:Z
n5:aktivity
Z(MSM0021622410)
n5:cisloPeriodika
1
n5:dodaniDat
n13:2010
n5:domaciTvurceVysledku
Pevec, Andrej n12:2274329 n12:1424343
n5:druhVysledku
n17:J
n5:duvernostUdaju
n9:S
n5:entitaPredkladatele
n14:predkladatel
n5:idSjednocenehoVysledku
398814
n5:idVysledku
RIV/00216224:14310/08:00025750
n5:jazykVysledku
n16:eng
n5:klicovaSlova
Titanium; Phosphonate; Crystal structure; Hydrogen bond
n5:klicoveSlovo
n6:Phosphonate n6:Crystal%20structure n6:Hydrogen%20bond n6:Titanium
n5:kodStatuVydavatele
NL - Nizozemsko
n5:kontrolniKodProRIV
[ACEBE2FD2750]
n5:nazevZdroje
Inorganic Chemistry Communication
n5:obor
n18:CA
n5:pocetDomacichTvurcuVysledku
3
n5:pocetTvurcuVysledku
4
n5:rokUplatneniVysledku
n13:2008
n5:svazekPeriodika
11
n5:tvurceVysledku
Pevec, Andrej Nečas, Marek Demsar, Alojz Pinkas, Jiří
n5:wos
000253105200002
n5:zamer
n15:MSM0021622410
s:issn
1387-7003
s:numberOfPages
3
n10:organizacniJednotka
14310