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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F06%3A00015583%21RIV10-MSM-14310___
rdf:type
skos:Concept n9:Vysledek
dcterms:description
A series of binuclear complexes of a general formula [(dppbO2)Ln(NO3)3(l-dppbO2)Ln(NO3)3(dppbO2)] (Ln = Pr (1), Nd (2), Sm (3), Dy (4), Lu (5)) were prepared by reacting bis(diphenylphosphino)butane dioxide (dppbO2) with lanthanide nitrates under solvothermal conditions. All compounds were characterized by analytical and spectroscopic techniques, such as infrared spectroscopy and mass spectrometry with electrospray ionization, and their molecular structures were determined by single crystal X-ray diffraction analysis in four cases. In contrast to the majority of lanthanide complexes with bis(diphenylphosphino)ethane dioxide which were previously reported as 2D polymeric networks, the present compounds are strictly molecular. This is evidently manifestation of the longer and flexible ligand backbone that allows a chelating binding mode. A series of binuclear complexes of a general formula [(dppbO2)Ln(NO3)3(l-dppbO2)Ln(NO3)3(dppbO2)] (Ln = Pr (1), Nd (2), Sm (3), Dy (4), Lu (5)) were prepared by reacting bis(diphenylphosphino)butane dioxide (dppbO2) with lanthanide nitrates under solvothermal conditions. All compounds were characterized by analytical and spectroscopic techniques, such as infrared spectroscopy and mass spectrometry with electrospray ionization, and their molecular structures were determined by single crystal X-ray diffraction analysis in four cases. In contrast to the majority of lanthanide complexes with bis(diphenylphosphino)ethane dioxide which were previously reported as 2D polymeric networks, the present compounds are strictly molecular. This is evidently manifestation of the longer and flexible ligand backbone that allows a chelating binding mode.
dcterms:title
Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide
skos:prefLabel
Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide
skos:notation
RIV/00216224:14310/06:00015583!RIV10-MSM-14310___
n3:aktivita
n11:P n11:Z
n3:aktivity
P(GA203/04/0296), Z(MSM0021622410), Z(MSM0021622415)
n3:cisloPeriodika
3
n3:dodaniDat
n10:2010
n3:domaciTvurceVysledku
n15:2274329 n15:4568567 n15:1424343 n15:8363269
n3:druhVysledku
n13:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
466931
n3:idVysledku
RIV/00216224:14310/06:00015583
n3:jazykVysledku
n19:eng
n3:klicovaSlova
lanthanide complexes coordination polymers
n3:klicoveSlovo
n17:lanthanide%20complexes%20coordination%20polymers
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[7FF02AE7F9E4]
n3:nazevZdroje
Polyhedron
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n6:GA203%2F04%2F0296
n3:rokUplatneniVysledku
n10:2006
n3:svazekPeriodika
25
n3:tvurceVysledku
Zdráhal, Zbyněk Spíchal, Zdeněk Nečas, Marek Pinkas, Jiří
n3:wos
000248633900025
n3:zamer
n4:MSM0021622415 n4:MSM0021622410
s:issn
0277-5387
s:numberOfPages
6
n5:organizacniJednotka
14310