This HTML5 document contains 46 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n16http://localhost/temp/predkladatel/
n6http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n17http://linked.opendata.cz/ontology/domain/vavai/
n8http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n5http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216224%3A14310%2F04%3A00009947%21RIV09-MSM-14310___/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n9http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n18http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n7http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F04%3A00009947%21RIV09-MSM-14310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Intramolekulární tripletový přenos energie u krátkých bichromoforních aminokyselin Efficiencies of the intramolecular triplet-triplet energy transfer (ITET) in various bichromophoric amino acids (glycine, valine, phenylalanine, and sarcosine), dipeptides (glycylglycine, phenylalanylphenylalanine), and a simple diester, with the benzoyl and naphthyl terminal groups serving as donor and acceptor, respectively, have been determined by the steady-state photokinetic measurements. The magnitude of the transfer rate constants (>10 exp8 s-1) and the number of bonds separating the chromophores (8 or 11 atoms) suggest a through-space exothermic exchange mechanism in all cases. The influence of interchromophore distance, the character of the connecting chain as well as of side chains, was evaluated. While the most efficient energy transfer was found in a flexible diester and in valine- and sarcosine-based molecules due to the steric effect of the side hydrocarbon groups, the benzyl groups in the phenylalanine and phenylalanylphenylalanine-based bichromophores had a suppressing effect on ITE Efficiencies of the intramolecular triplet-triplet energy transfer (ITET) in various bichromophoric amino acids (glycine, valine, phenylalanine, and sarcosine), dipeptides (glycylglycine, phenylalanylphenylalanine), and a simple diester, with the benzoyl and naphthyl terminal groups serving as donor and acceptor, respectively, have been determined by the steady-state photokinetic measurements. The magnitude of the transfer rate constants (>10 exp8 s-1) and the number of bonds separating the chromophores (8 or 11 atoms) suggest a through-space exothermic exchange mechanism in all cases. The influence of interchromophore distance, the character of the connecting chain as well as of side chains, was evaluated. While the most efficient energy transfer was found in a flexible diester and in valine- and sarcosine-based molecules due to the steric effect of the side hydrocarbon groups, the benzyl groups in the phenylalanine and phenylalanylphenylalanine-based bichromophores had a suppressing effect on ITE
dcterms:title
Intramolecular Triplet-Triplet Energy Transfer in Short Flexible Bichromophoric Amino Acids, Dipeptides and Carboxylic Acid Diester Intramolekulární tripletový přenos energie u krátkých bichromoforních aminokyselin Intramolecular Triplet-Triplet Energy Transfer in Short Flexible Bichromophoric Amino Acids, Dipeptides and Carboxylic Acid Diester
skos:prefLabel
Intramolekulární tripletový přenos energie u krátkých bichromoforních aminokyselin Intramolecular Triplet-Triplet Energy Transfer in Short Flexible Bichromophoric Amino Acids, Dipeptides and Carboxylic Acid Diester Intramolecular Triplet-Triplet Energy Transfer in Short Flexible Bichromophoric Amino Acids, Dipeptides and Carboxylic Acid Diester
skos:notation
RIV/00216224:14310/04:00009947!RIV09-MSM-14310___
n3:aktivita
n10:Z
n3:aktivity
Z(MSM 143100005)
n3:cisloPeriodika
4
n3:dodaniDat
n7:2009
n3:domaciTvurceVysledku
n6:9520775 n6:1626418 n6:1594974 n6:9309616
n3:druhVysledku
n15:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
568790
n3:idVysledku
RIV/00216224:14310/04:00009947
n3:jazykVysledku
n18:eng
n3:klicovaSlova
photochemistry; energy transfer
n3:klicoveSlovo
n9:photochemistry n9:energy%20transfer
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[4932A523AEAB]
n3:nazevZdroje
Collect. Czech. Chem. Commun.
n3:obor
n13:CC
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n7:2004
n3:svazekPeriodika
69
n3:tvurceVysledku
Heger, Dominik Kříž, Zdeněk Klán, Petr Zabadal, Miroslav
n3:wos
000220854200004
n3:zamer
n8:MSM%20143100005
s:issn
0010-0765
s:numberOfPages
21
n16:organizacniJednotka
14310