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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F03%3A00008231%21RIV08-AV0-14310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
Elimination voltammetry with linear scan (EVLS) has been applied to the resolution of reduction signals of adenine and cytosine in short synthetic homo-oligodeoxynucleotides (dA9 and dC9). In comparison with the common electrochemical methods (linear sweep, differential pulse, and square wave voltammetry) EVLS enables to resolve the overlapped signals by using the function which eliminates the charging and kinetic currents ( , ) and conserves the diffusion current ( ). For the adsorbed electroactive substance, this elimination function gives a well readable peak-counterpeak which has successfully been utilized to the analysis of overlapped reduction signals of adenine and cytosine on hanging mercury drop electrode (HMDE). The height and potential of signals studied were affected by the dC9/dA9 ratio, the time of accumulation, the stirring speed during the adsorption, and pH. Our results showed that EVLS in connection with the adsorption procedure is a useful tool for qualitative and quantitative studi Elimination voltammetry with linear scan (EVLS) has been applied to the resolution of reduction signals of adenine and cytosine in short synthetic homo-oligodeoxynucleotides (dA9 and dC9). In comparison with the common electrochemical methods (linear sweep, differential pulse, and square wave voltammetry) EVLS enables to resolve the overlapped signals by using the function which eliminates the charging and kinetic currents ( , ) and conserves the diffusion current ( ). For the adsorbed electroactive substance, this elimination function gives a well readable peak-counterpeak which has successfully been utilized to the analysis of overlapped reduction signals of adenine and cytosine on hanging mercury drop electrode (HMDE). The height and potential of signals studied were affected by the dC9/dA9 ratio, the time of accumulation, the stirring speed during the adsorption, and pH. Our results showed that EVLS in connection with the adsorption procedure is a useful tool for qualitative and quantitative studi Elimination voltammetry with linear scan (EVLS) has been applied to the resolution of reduction signals of adenine and cytosine in short synthetic homo-oligodeoxynucleotides (dA9 and dC9). In comparison with the common electrochemical methods (linear sweep, differential pulse, and square wave voltammetry) EVLS enables to resolve the overlapped signals by using the function which eliminates the charging and kinetic currents ( , ) and conserves the diffusion current ( ). For the adsorbed electroactive substance, this elimination function gives a well readable peak-counterpeak which has successfully been utilized to the analysis of overlapped reduction signals of adenine and cytosine on hanging mercury drop electrode (HMDE). The height and potential of signals studied were affected by the dC9/dA9 ratio, the time of accumulation, the stirring speed during the adsorption, and pH. Our results showed that EVLS in connection with the adsorption procedure is a useful tool for qualitative and quantitative studi
dcterms:title
Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9 Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9 Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9
skos:prefLabel
Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9 Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9 Application of Elimination Voltammetry to the Resolution of Adenine and Cytosine Signals in Oligonucleotides. I. Homo-oligodeoxynucleotides dA9 and dC9
skos:notation
RIV/00216224:14310/03:00008231!RIV08-AV0-14310___
n3:strany
1529-1535
n3:aktivita
n4:Z n4:P
n3:aktivity
P(GA203/02/0422), P(GV204/97/K084), P(IAA1163201), Z(AV0Z5004920)
n3:cisloPeriodika
15
n3:dodaniDat
n16:2008
n3:domaciTvurceVysledku
n9:1863770 n9:3790185 n9:4637844
n3:druhVysledku
n7:J
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
598856
n3:idVysledku
RIV/00216224:14310/03:00008231
n3:jazykVysledku
n10:eng
n3:klicovaSlova
Reduction of adenine and cytosine in oligonucleotides; mercury electrode; elimination voltammetry with linear scan; dC9 and dA9
n3:klicoveSlovo
n8:dC9%20and%20dA9 n8:mercury%20electrode n8:elimination%20voltammetry%20with%20linear%20scan n8:Reduction%20of%20adenine%20and%20cytosine%20in%20oligonucleotides
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[E6D01265D6A0]
n3:nazevZdroje
Electroanalysis
n3:obor
n14:CG
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n11:GV204%2F97%2FK084 n11:IAA1163201 n11:GA203%2F02%2F0422
n3:rokUplatneniVysledku
n16:2003
n3:svazekPeriodika
19
n3:tvurceVysledku
Postbieglová, Irena Jelen, František Trnková, Libuše
n3:zamer
n17:AV0Z5004920
s:issn
1040-0397
s:numberOfPages
7
n13:organizacniJednotka
14310