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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F02%3A00007021%21RIV08-MSM-14310___
rdf:type
skos:Concept n14:Vysledek
dcterms:description
The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2]. The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2]. The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2].
dcterms:title
Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations
skos:prefLabel
Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations
skos:notation
RIV/00216224:14310/02:00007021!RIV08-MSM-14310___
n3:strany
91
n3:aktivita
n11:Z n11:P
n3:aktivity
P(OC D10.20), Z(MSM 143100011)
n3:dodaniDat
n4:2008
n3:domaciTvurceVysledku
n10:2333368 n10:5305179
n3:druhVysledku
n20:D
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
667330
n3:idVysledku
RIV/00216224:14310/02:00007021
n3:jazykVysledku
n19:eng
n3:klicovaSlova
chiral recognition; microwave irradiation; racemization
n3:klicoveSlovo
n17:chiral%20recognition n17:microwave%20irradiation n17:racemization
n3:kontrolniKodProRIV
[05F952AA9907]
n3:mistoKonaniAkce
8.-12.9.2002; Hamburg, Německo
n3:mistoVydani
Hamburg, Německo
n3:nazevZdroje
Book of Abstracts from the 14th International Symposium on Chirality
n3:obor
n16:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n6:OC%20D10.20
n3:rokUplatneniVysledku
n4:2002
n3:tvurceVysledku
Potáček, Milan Navrátilová, Hana
n3:typAkce
n21:WRD
n3:zahajeniAkce
2002-01-01+01:00
n3:zamer
n15:MSM%20143100011
s:numberOfPages
1
n9:hasPublisher
Hamburg University
n18:organizacniJednotka
14310