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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F02%3A00006431%21RIV09-MSM-14310___
rdf:type
n12:Vysledek skos:Concept
dcterms:description
Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. Continuing our systematic 15N NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The 15N NMR chemical shifts and 15N,1H long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed.
dcterms:title
Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2
skos:prefLabel
Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2 Isoquinoline alkaloids: a 15N NMR and x-ray study. Part 2
skos:notation
RIV/00216224:14310/02:00006431!RIV09-MSM-14310___
n3:aktivita
n18:P
n3:aktivity
P(LN00A016)
n3:cisloPeriodika
11
n3:dodaniDat
n5:2009
n3:domaciTvurceVysledku
n6:7253478 n6:3682455 n6:8533113 n6:8675058
n3:druhVysledku
n17:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
649805
n3:idVysledku
RIV/00216224:14310/02:00006431
n3:jazykVysledku
n13:eng
n3:klicovaSlova
alkaloid; isoquinoline; 15N NMR; X-ray
n3:klicoveSlovo
n8:isoquinoline n8:X-ray n8:alkaloid n8:15N%20NMR
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[AE5079AA9815]
n3:nazevZdroje
Magnetic Resonance in Chemistry
n3:obor
n16:CC
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
6
n3:projekt
n10:LN00A016
n3:rokUplatneniVysledku
n5:2002
n3:svazekPeriodika
40
n3:tvurceVysledku
Dostál, Jiří Slavík, Jiří Dommisse, Roger Marek, Radek Táborská, Eva Marek, Jaromír
n3:wos
000178816300002
s:issn
0749-1581
s:numberOfPages
6
n14:organizacniJednotka
14310