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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F01%3A00005416%21RIV%2F2002%2FMSM%2F143102%2FN
rdf:type
n8:Vysledek skos:Concept
dcterms:description
The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity.Two selected functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linear. The peak potentials differ in these elimination functions. The difference in EVLS peak potentials gives the possibility to evaluate .EVLS contributes to the resolution of cathodic signals of purine and pyrimidine bases at very ne The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity.Two selected functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linear. The peak potentials differ in these elimination functions. The difference in EVLS peak potentials gives the possibility to evaluate .EVLS contributes to the resolution of cathodic signals of purine and pyrimidine bases at very ne
dcterms:title
Elimination Voltammetry of Adenine and Cytosine Mixtures Elimination Voltammetry of Adenine and Cytosine Mixtures
skos:prefLabel
Elimination Voltammetry of Adenine and Cytosine Mixtures Elimination Voltammetry of Adenine and Cytosine Mixtures
skos:notation
RIV/00216224:14310/01:00005416!RIV/2002/MSM/143102/N
n3:strany
131
n3:aktivita
n4:Z n4:P
n3:aktivity
P(GV204/97/K084), Z(MSM 143100011)
n3:cisloPeriodika
54
n3:dodaniDat
n6:2002
n3:domaciTvurceVysledku
n10:3730832 n10:3790185 n10:6116957
n3:druhVysledku
n9:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
679253
n3:idVysledku
RIV/00216224:14310/01:00005416
n3:jazykVysledku
n13:eng
n3:klicovaSlova
Elimination voltammetry with linear scan, cytosine, adenine, reduction of bases, hydrogen evolution
n3:klicoveSlovo
n5:cytosine n5:reduction%20of%20bases n5:Elimination%20voltammetry%20with%20linear%20scan n5:hydrogen%20evolution n5:adenine
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[902D8F8967F3]
n3:nazevZdroje
Bioelectrochemistry
n3:obor
n19:CG
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n12:GV204%2F97%2FK084
n3:rokUplatneniVysledku
n6:2001
n3:svazekPeriodika
2001
n3:tvurceVysledku
Friml, Jiří Dračka, Oldřich Trnková, Libuše
n3:zamer
n14:MSM%20143100011
s:issn
1567-5394
s:numberOfPages
6
n15:organizacniJednotka
14310