This HTML5 document contains 48 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n18http://localhost/temp/predkladatel/
n7http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n11http://linked.opendata.cz/ontology/domain/vavai/
n13http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n6http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216224%3A14310%2F01%3A00004581%21RIV09-MSM-14310___/
n5http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n17http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n16http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F01%3A00004581%21RIV09-MSM-14310___
rdf:type
skos:Concept n11:Vysledek
dcterms:description
Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography. Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography. Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography.
dcterms:title
On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.
skos:prefLabel
On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.
skos:notation
RIV/00216224:14310/01:00004581!RIV09-MSM-14310___
n4:aktivita
n15:Z
n4:aktivity
Z(MSM 143100011)
n4:cisloPeriodika
20
n4:dodaniDat
n16:2009
n4:domaciTvurceVysledku
n7:8100020 n7:9499067 n7:9247742 n7:1424343
n4:druhVysledku
n8:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n6:predkladatel
n4:idSjednocenehoVysledku
690020
n4:idVysledku
RIV/00216224:14310/01:00004581
n4:jazykVysledku
n17:eng
n4:klicovaSlova
four-membered heterocycle; five-membered heterocycle; diazadiphosphetidine; chlorodithiophosphoric acid pyridiniumbetaine
n4:klicoveSlovo
n5:five-membered%20heterocycle n5:chlorodithiophosphoric%20acid%20pyridiniumbetaine n5:diazadiphosphetidine n5:four-membered%20heterocycle
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[C5966E93A0F4]
n4:nazevZdroje
Polyhedron
n4:obor
n10:CA
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
4
n4:rokUplatneniVysledku
n16:2001
n4:svazekPeriodika
2001
n4:tvurceVysledku
Příhoda, Jiří Žák, Zdirad Nečas, Marek Janča, Michal
n4:wos
000172076300008
n4:zamer
n13:MSM%20143100011
s:issn
0277-5387
s:numberOfPages
6
n18:organizacniJednotka
14310