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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F14%3A10286169%21RIV15-MSM-11320___
rdf:type
n10:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1063/1.4903937
dcterms:description
Hybrid diamond-organic interfaces are considered attractive for diverse applications ranging from electronics and energy conversion to medicine. Here we use time-resolved and time-integrated photoluminescence spectroscopy in visible spectral range (380-700 nm) to study electronic processes in H-terminated nanocrystalline diamond films (NCD) with 150 nm thin, electrochemically deposited polypyrrole (PPy) layer. We observe changes in dynamics of NCD photoluminescence as well as in its time-integrated spectra after polymer deposition. The effect is reversible. We propose a model where the PPy layer on the NCD surface promotes spatial separation of photo-generated charge carriers both in non-diamond carbon phase and in bulk diamond. By comparing different NCD thicknesses we show that the effect goes as much as 200 nm deep inside the NCD film. (C) 2014 AIP Publishing LLC. Hybrid diamond-organic interfaces are considered attractive for diverse applications ranging from electronics and energy conversion to medicine. Here we use time-resolved and time-integrated photoluminescence spectroscopy in visible spectral range (380-700 nm) to study electronic processes in H-terminated nanocrystalline diamond films (NCD) with 150 nm thin, electrochemically deposited polypyrrole (PPy) layer. We observe changes in dynamics of NCD photoluminescence as well as in its time-integrated spectra after polymer deposition. The effect is reversible. We propose a model where the PPy layer on the NCD surface promotes spatial separation of photo-generated charge carriers both in non-diamond carbon phase and in bulk diamond. By comparing different NCD thicknesses we show that the effect goes as much as 200 nm deep inside the NCD film. (C) 2014 AIP Publishing LLC.
dcterms:title
Electrochemically grafted polypyrrole changes photoluminescence of electronic states inside nanocrystalline diamond Electrochemically grafted polypyrrole changes photoluminescence of electronic states inside nanocrystalline diamond
skos:prefLabel
Electrochemically grafted polypyrrole changes photoluminescence of electronic states inside nanocrystalline diamond Electrochemically grafted polypyrrole changes photoluminescence of electronic states inside nanocrystalline diamond
skos:notation
RIV/00216208:11320/14:10286169!RIV15-MSM-11320___
n3:aktivita
n19:S n19:P n19:I
n3:aktivity
I, P(GBP108/12/G108), P(LM2011026), S
n3:cisloPeriodika
22
n3:dodaniDat
n9:2015
n3:domaciTvurceVysledku
n5:7526857 n5:8499675
n3:druhVysledku
n16:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
14122
n3:idVysledku
RIV/00216208:11320/14:10286169
n3:jazykVysledku
n8:eng
n3:klicovaSlova
phase; luminescence; spectroscopy; carbon; thin-films
n3:klicoveSlovo
n7:thin-films n7:luminescence n7:carbon n7:phase n7:spectroscopy
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[F0FD5EEF2F59]
n3:nazevZdroje
Journal of Applied Physics
n3:obor
n15:BM
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:projekt
n11:LM2011026 n11:GBP108%2F12%2FG108
n3:rokUplatneniVysledku
n9:2014
n3:svazekPeriodika
116
n3:tvurceVysledku
Galář, Pavel Cermak, J. Malý, Petr Kromka, A. Rezek, B.
n3:wos
000346266300012
s:issn
0021-8979
s:numberOfPages
6
n6:doi
10.1063/1.4903937
n20:organizacniJednotka
11320