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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F14%3A10271606%21RIV15-MSM-11320___
rdf:type
n14:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1002/chem.201304423
dcterms:description
The transformation of Mn-II glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)(2)](n) (1) and discrete mononuclear phase [Mn(glc)(2)(H2O)(2)] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of Mn-II glycolates from the maximum of 6.9Jkg(-1)K(-1) in 1 to 60.3Jkg(-1)K(-1) in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic density for 3d-type magnetic refrigerants. The transformation of Mn-II glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)(2)](n) (1) and discrete mononuclear phase [Mn(glc)(2)(H2O)(2)] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of Mn-II glycolates from the maximum of 6.9Jkg(-1)K(-1) in 1 to 60.3Jkg(-1)K(-1) in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic density for 3d-type magnetic refrigerants.
dcterms:title
Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules
skos:prefLabel
Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules
skos:notation
RIV/00216208:11320/14:10271606!RIV15-MSM-11320___
n3:aktivita
n15:P n15:I
n3:aktivity
I, P(LM2011025)
n3:cisloPeriodika
11
n3:dodaniDat
n4:2015
n3:domaciTvurceVysledku
n17:8997322 n17:6586805
n3:druhVysledku
n16:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
48854
n3:idVysledku
RIV/00216208:11320/14:10271606
n3:jazykVysledku
n13:eng
n3:klicovaSlova
manganese; magnetocaloric effect; magnetic properties; glycolates; coordination polymers
n3:klicoveSlovo
n5:magnetic%20properties n5:magnetocaloric%20effect n5:coordination%20polymers n5:manganese n5:glycolates
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[7029A409D624]
n3:nazevZdroje
Chemistry - A European Journal
n3:obor
n11:BM
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
9
n3:projekt
n20:LM2011025
n3:rokUplatneniVysledku
n4:2014
n3:svazekPeriodika
20
n3:tvurceVysledku
Vrabel, Peter Guo, Fu-Sheng Tong, Ming-Liang Chen, Yan-Cong Prokleška, Jan Orendac, Martin Liu, Jun-Liang Leng, Ji-Dong Sechovský, Vladimír
n3:wos
000332043500010
s:issn
0947-6539
s:numberOfPages
7
n12:doi
10.1002/chem.201304423
n10:organizacniJednotka
11320