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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F13%3A10189776%21RIV14-MSM-11320___
rdf:type
skos:Concept n19:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1007/s10858-013-9763-5
dcterms:description
Carbon-13 relaxation data are reported for exocyclic groups of hexopyranosyl sugar residues in the repeating unit within the Escherichia coli O91 O-antigen polysaccharide in a dilute D2O solution. The measurements of T (1), T (2) and heteronuclear nuclear Overhauser enhancements were carried out at 310 K at two magnetic fields (16.4 T, 21.1 T). The data were analyzed using the standard and extended Lipari-Szabo models, as well as a conformational jump model. The extended version of the Lipari-Szabo and the two-site jump models were most successful for the hydroxymethyl groups of Gal and GlcNAc sugar residues. Different dynamics was found for the hydroxymethyl groups associated with different configurations (d-gluco, d-galacto) of the sugar residues, the latter being faster than the former. Carbon-13 relaxation data are reported for exocyclic groups of hexopyranosyl sugar residues in the repeating unit within the Escherichia coli O91 O-antigen polysaccharide in a dilute D2O solution. The measurements of T (1), T (2) and heteronuclear nuclear Overhauser enhancements were carried out at 310 K at two magnetic fields (16.4 T, 21.1 T). The data were analyzed using the standard and extended Lipari-Szabo models, as well as a conformational jump model. The extended version of the Lipari-Szabo and the two-site jump models were most successful for the hydroxymethyl groups of Gal and GlcNAc sugar residues. Different dynamics was found for the hydroxymethyl groups associated with different configurations (d-gluco, d-galacto) of the sugar residues, the latter being faster than the former.
dcterms:title
Dynamics of exocyclic groups in the Escherichia coli O91 O-antigen polysaccharide in solution studied by carbon-13 NMR relaxation Dynamics of exocyclic groups in the Escherichia coli O91 O-antigen polysaccharide in solution studied by carbon-13 NMR relaxation
skos:prefLabel
Dynamics of exocyclic groups in the Escherichia coli O91 O-antigen polysaccharide in solution studied by carbon-13 NMR relaxation Dynamics of exocyclic groups in the Escherichia coli O91 O-antigen polysaccharide in solution studied by carbon-13 NMR relaxation
skos:notation
RIV/00216208:11320/13:10189776!RIV14-MSM-11320___
n19:predkladatel
n20:orjk%3A11320
n3:aktivita
n14:S n14:I
n3:aktivity
I, S
n3:cisloPeriodika
1
n3:dodaniDat
n9:2014
n3:domaciTvurceVysledku
n15:4552202
n3:druhVysledku
n13:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
70963
n3:idVysledku
RIV/00216208:11320/13:10189776
n3:jazykVysledku
n12:eng
n3:klicovaSlova
Two-site jump model; Model free approach; NMR spectroscopy; Biopolymer; Polysaccharide; Carbohydrates
n3:klicoveSlovo
n10:NMR%20spectroscopy n10:Biopolymer n10:Polysaccharide n10:Carbohydrates n10:Model%20free%20approach n10:Two-site%20jump%20model
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[C5D498CEDA53]
n3:nazevZdroje
Journal of Biomolecular NMR
n3:obor
n4:BO
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n9:2013
n3:svazekPeriodika
57
n3:tvurceVysledku
Kowalewski, Jozef Widmalm, Goran Šoltésová, Mária
n3:wos
000323673800005
s:issn
0925-2738
s:numberOfPages
9
n16:doi
10.1007/s10858-013-9763-5
n8:organizacniJednotka
11320