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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F12%3A10130886%21RIV13-GA0-11320___
rdf:type
n11:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1098/rsta.2012.0098
dcterms:description
Formation of H-3(+) via association of H+ with H-2 has been studied at low temperatures using a 22-pole radiofrequency trap. Operating at hydrogen number densities from 10(11) to 10(14) cm(-3), the contributions of radiative, k(r), and ternary, k(3), association have been extracted from the measured apparent binary rate coefficients, k* = k(r) + k(3)[H-2]. Surprisingly, k(3) is constant between 11 and 22 K, (2.6 +/- 0.8) x 10(-29) cm(6) s(-1), while radiative association decreases from k(r)(11 K)=(1.6 +/- 0.3) x 10(-16) cm(3) s(-1) to k(r)(28 K)= (5 +/- 2) x 10(-17) cm(3) s(-1). These results are in conflict with simple association models in which formation and stabilization of the complex are treated separately. Tentative explanations are based on the fact that, at low temperatures, only few partial waves contribute to the formation of the collision complex and that ternary association with H-2 may be quite inefficient because of the 'shared proton' structure of H-5(+). Formation of H-3(+) via association of H+ with H-2 has been studied at low temperatures using a 22-pole radiofrequency trap. Operating at hydrogen number densities from 10(11) to 10(14) cm(-3), the contributions of radiative, k(r), and ternary, k(3), association have been extracted from the measured apparent binary rate coefficients, k* = k(r) + k(3)[H-2]. Surprisingly, k(3) is constant between 11 and 22 K, (2.6 +/- 0.8) x 10(-29) cm(6) s(-1), while radiative association decreases from k(r)(11 K)=(1.6 +/- 0.3) x 10(-16) cm(3) s(-1) to k(r)(28 K)= (5 +/- 2) x 10(-17) cm(3) s(-1). These results are in conflict with simple association models in which formation and stabilization of the complex are treated separately. Tentative explanations are based on the fact that, at low temperatures, only few partial waves contribute to the formation of the collision complex and that ternary association with H-2 may be quite inefficient because of the 'shared proton' structure of H-5(+).
dcterms:title
Stabilization of H+-H-2 collision complexes between 11 and 28K Stabilization of H+-H-2 collision complexes between 11 and 28K
skos:prefLabel
Stabilization of H+-H-2 collision complexes between 11 and 28K Stabilization of H+-H-2 collision complexes between 11 and 28K
skos:notation
RIV/00216208:11320/12:10130886!RIV13-GA0-11320___
n11:predkladatel
n19:orjk%3A11320
n3:aktivita
n14:S n14:P
n3:aktivity
P(GA205/09/1183), P(GAP209/12/0233), P(OC10046), S
n3:cisloPeriodika
1978
n3:dodaniDat
n12:2013
n3:domaciTvurceVysledku
Zymak, Illia n6:9667334 n6:9707700 n6:2913623 Gerlich, Dieter Mulin, Dmytro
n3:druhVysledku
n7:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
170845
n3:idVysledku
RIV/00216208:11320/12:10130886
n3:jazykVysledku
n20:eng
n3:klicovaSlova
ion traps; association; H-3(+); H+; interstellar chemistry
n3:klicoveSlovo
n4:H%2B n4:interstellar%20chemistry n4:H-3%28%2B%29 n4:association n4:ion%20traps
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[C653E440244B]
n3:nazevZdroje
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
n3:obor
n17:BL
n3:pocetDomacichTvurcuVysledku
6
n3:pocetTvurcuVysledku
6
n3:projekt
n15:GA205%2F09%2F1183 n15:OC10046 n15:GAP209%2F12%2F0233
n3:rokUplatneniVysledku
n12:2012
n3:svazekPeriodika
370
n3:tvurceVysledku
Glosík, Juraj Jusko, Pavol Gerlich, Dieter Zymak, Illia Plašil, Radek Mulin, Dmytro
n3:wos
000309522800007
s:issn
1364-503X
s:numberOfPages
8
n21:doi
10.1098/rsta.2012.0098
n8:organizacniJednotka
11320