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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F12%3A10126312%21RIV13-GA0-11320___
rdf:type
skos:Concept n7:Vysledek
rdfs:seeAlso
http://www.mff.cuni.cz/veda/konference/wds/proc/pdf12/WDS12_307_f4_Radecki.pdf
dcterms:description
Aqueous solutions of poly(vinyl methyl ether) are known to undergo phase separation in dependence of temperature. The differential scanning calorimetry (DSC), high-resolution nuclear magnetic resonance (NMR) and optical microscopy (OM) methods have been used to study dynamical and structural changes during the phase separation. Results show strong dependence of DSC, NMR and OM parameters on polymer concentration and non-reversibility during heating and subsequent cooling process in the short time range. NMR data were used to construct van 't Hoff plots and changes of the enthalpy and entropy characterizing the phase transition were determined. Aqueous solutions of poly(vinyl methyl ether) are known to undergo phase separation in dependence of temperature. The differential scanning calorimetry (DSC), high-resolution nuclear magnetic resonance (NMR) and optical microscopy (OM) methods have been used to study dynamical and structural changes during the phase separation. Results show strong dependence of DSC, NMR and OM parameters on polymer concentration and non-reversibility during heating and subsequent cooling process in the short time range. NMR data were used to construct van 't Hoff plots and changes of the enthalpy and entropy characterizing the phase transition were determined.
dcterms:title
Spectroscopic Studies of Behaviour and Interactions in PVME/Water Mixtures Spectroscopic Studies of Behaviour and Interactions in PVME/Water Mixtures
skos:prefLabel
Spectroscopic Studies of Behaviour and Interactions in PVME/Water Mixtures Spectroscopic Studies of Behaviour and Interactions in PVME/Water Mixtures
skos:notation
RIV/00216208:11320/12:10126312!RIV13-GA0-11320___
n7:predkladatel
n8:orjk%3A11320
n3:aktivita
n22:S n22:P
n3:aktivity
P(GA202/09/1281), S
n3:dodaniDat
n21:2013
n3:domaciTvurceVysledku
n10:7129017 n10:4036654
n3:druhVysledku
n16:D
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n20:predkladatel
n3:idSjednocenehoVysledku
170377
n3:idVysledku
RIV/00216208:11320/12:10126312
n3:jazykVysledku
n15:eng
n3:klicovaSlova
phase separation; poly(vinyl methyl ether); optical microscopy; nuclear magnetic resonance; differential scanning calorimetry
n3:klicoveSlovo
n4:optical%20microscopy n4:phase%20separation n4:differential%20scanning%20calorimetry n4:nuclear%20magnetic%20resonance n4:poly%28vinyl%20methyl%20ether%29
n3:kontrolniKodProRIV
[910AFBFDC247]
n3:mistoKonaniAkce
Praha
n3:mistoVydani
Praha
n3:nazevZdroje
WDS'12 Proceedings of Contributed Papers: Part III - Physics
n3:obor
n5:BM
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n11:GA202%2F09%2F1281
n3:rokUplatneniVysledku
n21:2012
n3:tvurceVysledku
Hanyková, Lenka Radecki, Marek
n3:typAkce
n17:EUR
n3:zahajeniAkce
2012-05-29+02:00
s:numberOfPages
6
n18:hasPublisher
Matfyzpress
n14:isbn
978-80-7378-226-9
n19:organizacniJednotka
11320