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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F10%3A10078914%21RIV11-GA0-11320___
rdf:type
n15:Vysledek skos:Concept
dcterms:description
We present an improved nonlocal resonance model for electron-HCl collisions. The short-range part of the model is fitted to ab initio electron-scattering eigenphase sums calculated using the Schwinger multichannel method, while the long-range part is based on the ab initio potential-energy curve of the bound anion HCl-. This model significantly improves the agreement of nonlocal resonance calculations with recent absolute experimental data on dissociative electron attachment cross sections for HCl and DCl. It also partly resolves an inconsistency in the temperature effect in dissociative electron attachment to HCl present in the literature. Finally, the present model reproduces all qualitative structures observed previously in elastic scattering and vibrational-excitation cross sections. We present an improved nonlocal resonance model for electron-HCl collisions. The short-range part of the model is fitted to ab initio electron-scattering eigenphase sums calculated using the Schwinger multichannel method, while the long-range part is based on the ab initio potential-energy curve of the bound anion HCl-. This model significantly improves the agreement of nonlocal resonance calculations with recent absolute experimental data on dissociative electron attachment cross sections for HCl and DCl. It also partly resolves an inconsistency in the temperature effect in dissociative electron attachment to HCl present in the literature. Finally, the present model reproduces all qualitative structures observed previously in elastic scattering and vibrational-excitation cross sections.
dcterms:title
Electron scattering in HCl: An improved nonlocal resonance model Electron scattering in HCl: An improved nonlocal resonance model
skos:prefLabel
Electron scattering in HCl: An improved nonlocal resonance model Electron scattering in HCl: An improved nonlocal resonance model
skos:notation
RIV/00216208:11320/10:10078914!RIV11-GA0-11320___
n3:aktivita
n8:P n8:Z
n3:aktivity
P(GA202/07/0833), Z(MSM0021620860)
n3:cisloPeriodika
4
n3:dodaniDat
n11:2011
n3:domaciTvurceVysledku
n9:2688263 n9:8070458 n9:2078805 n9:6207162
n3:druhVysledku
n10:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
256754
n3:idVysledku
RIV/00216208:11320/10:10078914
n3:jazykVysledku
n18:eng
n3:klicovaSlova
slow electrons; vibrational excitation; molecular-orbital methods; excitation cross-sections
n3:klicoveSlovo
n4:excitation%20cross-sections n4:molecular-orbital%20methods n4:slow%20electrons n4:vibrational%20excitation
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[9704D854E4CD]
n3:nazevZdroje
Physical Review A - Atomic Molecular and Optical Physics
n3:obor
n13:BG
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
7
n3:projekt
n16:GA202%2F07%2F0833
n3:rokUplatneniVysledku
n11:2010
n3:svazekPeriodika
81
n3:tvurceVysledku
Winstead, C. Horáček, Jiří Fedor, J. McKoy, V. Čížek, Martin Kolorenč, Přemysl Houfek, Karel
n3:wos
000277227300097
n3:zamer
n17:MSM0021620860
s:issn
1050-2947
s:numberOfPages
7
n19:organizacniJednotka
11320