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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F10%3A10071494%21RIV11-GA0-11320___
rdf:type
n13:Vysledek skos:Concept
dcterms:description
We have obtained the binary and the ternary electron-ion recombination rate coefficients and their temperature dependence for H3+ and D3+ ions (produced in the mixture He/Ar/parent-gas H2 or D2) in the afterglow plasma. A mechanism with two subsequent rate-determining steps is proposed to explain the observed ternary recombination rate. In the first step, in $H_3^+ + e$ (or $D_3^+ + e$) collision, a rotationally excited long-lived Rydberg molecule H3* (or D3*) is formed. In the following step this collides with a He atom of the buffer gas and this collision prevents the autoionization of H3* (or D3*). Lifetimes of H3* (or D3*) and corresponding ternary recombination rate coefficients have been calculated. The theoretical and measured binary and ternary recombination rate coefficients obtained for H3+ and D3+ ions are in good agreement. We have obtained the binary and the ternary electron-ion recombination rate coefficients and their temperature dependence for H3+ and D3+ ions (produced in the mixture He/Ar/parent-gas H2 or D2) in the afterglow plasma. A mechanism with two subsequent rate-determining steps is proposed to explain the observed ternary recombination rate. In the first step, in $H_3^+ + e$ (or $D_3^+ + e$) collision, a rotationally excited long-lived Rydberg molecule H3* (or D3*) is formed. In the following step this collides with a He atom of the buffer gas and this collision prevents the autoionization of H3* (or D3*). Lifetimes of H3* (or D3*) and corresponding ternary recombination rate coefficients have been calculated. The theoretical and measured binary and ternary recombination rate coefficients obtained for H3+ and D3+ ions are in good agreement.
dcterms:title
Binary and ternary recombination of H3+ and D3+ ions with electrons in low temperature plasma Binary and ternary recombination of H3+ and D3+ ions with electrons in low temperature plasma
skos:prefLabel
Binary and ternary recombination of H3+ and D3+ ions with electrons in low temperature plasma Binary and ternary recombination of H3+ and D3+ ions with electrons in low temperature plasma
skos:notation
RIV/00216208:11320/10:10071494!RIV11-GA0-11320___
n3:aktivita
n11:Z n11:S n11:P
n3:aktivity
P(GA202/07/0495), P(GA202/09/0642), P(GA205/09/1183), P(GD202/08/H057), S, Z(MSM0021620834)
n3:cisloPeriodika
17
n3:dodaniDat
n8:2011
n3:domaciTvurceVysledku
n5:6787703 n5:9417559 n5:6512895 n5:9667334 n5:2913623 n5:3847632 Korolov, Ihor n5:8133824
n3:druhVysledku
n16:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
248807
n3:idVysledku
RIV/00216208:11320/10:10071494
n3:jazykVysledku
n19:eng
n3:klicovaSlova
lifetime of Rydberg molecule; afterglow; plasma; He assisted ternary recombination; binary recombination; ions; H3+ and O3+ ions
n3:klicoveSlovo
n4:He%20assisted%20ternary%20recombination n4:binary%20recombination n4:lifetime%20of%20Rydberg%20molecule n4:afterglow n4:ions n4:H3%2B%20and%20O3%2B%20ions n4:plasma
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[29F8B242EE5B]
n3:nazevZdroje
Molecular Physics
n3:obor
n15:BL
n3:pocetDomacichTvurcuVysledku
8
n3:pocetTvurcuVysledku
9
n3:projekt
n14:GA202%2F09%2F0642 n14:GA202%2F07%2F0495 n14:GD202%2F08%2FH057 n14:GA205%2F09%2F1183
n3:rokUplatneniVysledku
n8:2010
n3:svazekPeriodika
108
n3:tvurceVysledku
Glosík, Juraj Plašil, Radek Korolov, Ihor Kokoouline, V. Dohnal, Petr Kotrík, Tomáš Hejduk, Michal Roučka, Štěpán Varju, Jozef
n3:wos
000281646900011
n3:zamer
n7:MSM0021620834
s:issn
0026-8976
s:numberOfPages
12
n6:organizacniJednotka
11320