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Statements

Subject Item
n2:RIV%2F00216208%3A11320%2F09%3A00206684%21RIV10-GA0-11320___
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Several new hydrides from the series R2Ni2InHx (R = La, Ce, Pr, Nd; x 4.5 - 5.0) were synthesized. They are based on initial compounds of the R2Ni2In type crystallizing in the Mo2FeB2-structure. So as to accommodate high amount of H atoms (x can theoretically reach the value of 6), the structure changes to orthorhombic, space group Pbam, while the unit-cell volume increases by 10-20 %. Nd2Ni2In was found antiferromagnetic, with a first order magnetic phase transition at TN = 8 K. Applied magnetic field moH { 0.3 T induces ferromagnetism. TN of Nd2Ni2InH4.5, which is a more regular antiferromagnet, is reduced to 5 K. Several new hydrides from the series R2Ni2InHx (R = La, Ce, Pr, Nd; x 4.5 - 5.0) were synthesized. They are based on initial compounds of the R2Ni2In type crystallizing in the Mo2FeB2-structure. So as to accommodate high amount of H atoms (x can theoretically reach the value of 6), the structure changes to orthorhombic, space group Pbam, while the unit-cell volume increases by 10-20 %. Nd2Ni2In was found antiferromagnetic, with a first order magnetic phase transition at TN = 8 K. Applied magnetic field moH { 0.3 T induces ferromagnetism. TN of Nd2Ni2InH4.5, which is a more regular antiferromagnet, is reduced to 5 K.
dcterms:title
Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type
skos:prefLabel
Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type
skos:notation
RIV/00216208:11320/09:00206684!RIV10-GA0-11320___
n3:aktivita
n10:Z n10:P
n3:aktivity
P(GA202/07/0418), Z(MSM0021620834)
n3:cisloPeriodika
1-2
n3:dodaniDat
n6:2010
n3:domaciTvurceVysledku
n9:3399087 Miliyanchuk, Khrystyna Stelmakhovych, Olha
n3:druhVysledku
n15:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
323216
n3:idVysledku
RIV/00216208:11320/09:00206684
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Large; Hydrogen; Capacity; Hydrides; R2Ni2In-H; Structure; Type
n3:klicoveSlovo
n8:Hydrogen n8:Large n8:R2Ni2In-H n8:Type n8:Structure n8:Hydrides n8:Capacity
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[9B6912F75147]
n3:nazevZdroje
Journal of Alloys and Compounds
n3:obor
n16:BM
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:projekt
n18:GA202%2F07%2F0418
n3:rokUplatneniVysledku
n6:2009
n3:svazekPeriodika
477
n3:tvurceVysledku
Kalychak, Y. Dzevenko, M. Miliyanchuk, Khrystyna Akselrud, L. Havela, Ladislav Stelmakhovych, Olha Filinchuk, Y.
n3:wos
000266386400044
n3:zamer
n17:MSM0021620834
s:issn
0925-8388
s:numberOfPages
6
n7:organizacniJednotka
11320