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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F14%3A10272020%21RIV15-MSM-11310___
rdf:type
skos:Concept n15:Vysledek
rdfs:seeAlso
http://przyrbwn.icm.edu.pl/APP/ABSTR/126/a126-1-149.html
dcterms:description
In the present work we have focused on the preparation and magnetic study of coordination polymer formed by Gd(III) cations as nodes and formate (HCOO-; FOR) anions as charge compensating linkers. The prepared complex with formula {[Gd(mu3-FOR)3]}(n) was characterized by single-crystal X-ray diffraction, and high-energy powder X-ray diffraction. The structural study showed that complex is formed by 3D polymeric network with the shortest Gd-Gd, distances of 3.998 angstrom. The magnetic properties of the complex were studied by magnetic susceptibility chi(M)(T) and magnetization M(H) measurements. The results show on the weak antiferromagnetic coupling at low temperatures represented by the Weiss constant theta = -0.468 K. The value of effective magnetic moment mu(eff) = 7.57 mu(B), which was estimated from the experimental data is close to the theoretical value for systems with S = 7/2. Correlation between crystal structure of complexes and magnetic properties is presented. In the present work we have focused on the preparation and magnetic study of coordination polymer formed by Gd(III) cations as nodes and formate (HCOO-; FOR) anions as charge compensating linkers. The prepared complex with formula {[Gd(mu3-FOR)3]}(n) was characterized by single-crystal X-ray diffraction, and high-energy powder X-ray diffraction. The structural study showed that complex is formed by 3D polymeric network with the shortest Gd-Gd, distances of 3.998 angstrom. The magnetic properties of the complex were studied by magnetic susceptibility chi(M)(T) and magnetization M(H) measurements. The results show on the weak antiferromagnetic coupling at low temperatures represented by the Weiss constant theta = -0.468 K. The value of effective magnetic moment mu(eff) = 7.57 mu(B), which was estimated from the experimental data is close to the theoretical value for systems with S = 7/2. Correlation between crystal structure of complexes and magnetic properties is presented.
dcterms:title
Structure and Magnetic Properties of Three-Dimensional Gadolinium-Based Hybrid Framework Structure and Magnetic Properties of Three-Dimensional Gadolinium-Based Hybrid Framework
skos:prefLabel
Structure and Magnetic Properties of Three-Dimensional Gadolinium-Based Hybrid Framework Structure and Magnetic Properties of Three-Dimensional Gadolinium-Based Hybrid Framework
skos:notation
RIV/00216208:11310/14:10272020!RIV15-MSM-11310___
n4:aktivita
n19:I
n4:aktivity
I
n4:cisloPeriodika
1
n4:dodaniDat
n9:2015
n4:domaciTvurceVysledku
n14:3157962
n4:druhVysledku
n18:J
n4:duvernostUdaju
n16:S
n4:entitaPredkladatele
n11:predkladatel
n4:idSjednocenehoVysledku
47902
n4:idVysledku
RIV/00216208:11310/14:10272020
n4:jazykVysledku
n7:eng
n4:klicovaSlova
X-ray diffraction; polymer; magnetic properties; gadolinium
n4:klicoveSlovo
n10:polymer n10:X-ray%20diffraction n10:gadolinium n10:magnetic%20properties
n4:kodStatuVydavatele
PL - Polská republika
n4:kontrolniKodProRIV
[47AF605876E4]
n4:nazevZdroje
Acta Physica Polonica A
n4:obor
n17:BM
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
5
n4:rokUplatneniVysledku
n9:2014
n4:svazekPeriodika
126
n4:tvurceVysledku
Bednarčík, Jozef Císařová, Ivana Zeleňáková, Adriana Almáši, Miroslav Zeleňák, Vladimír
n4:wos
000339833100150
s:issn
0587-4246
s:numberOfPages
2
n8:doi
10.12693/APhysPolA.126.308
n12:organizacniJednotka
11310