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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F14%3A10218651%21RIV15-MSM-11310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Over the last decade, intensive research is being carried out towards the development of %22green%22 electrochemical sensors. Bismuth, antimony and tin electrodes have been proposed as potential substitutes of mercury electrodes in electrochemical stripping analysis of trace metals. The main advantage of these metals as electrode materials is their lower toxicity compared to mercury. Among the different configuration of bismuth, antimony and tin electrodes, one of the most attractive involves the modification of a support material with a bismuth, antimony or tin precursor compound (oxide, hydroxide or sparingly soluble salt). When the electrode is polarized to a sufficiently cathodic potential, the metal precursor is reduced to the respective metal which forms a thin %22film%22 on the surface of the support material. The present article is an overview of the existing state-of-the-art in the field of bismuth, antimony and tin precursor-modified sensors. This review covers and critically discusses the various fabrication approaches (support materials, types of precursor compounds, modification approaches, precursor reduction methods) and also lists typical applications of these precursor-modified sensors to electrochemical stripping analysis of metals. Over the last decade, intensive research is being carried out towards the development of %22green%22 electrochemical sensors. Bismuth, antimony and tin electrodes have been proposed as potential substitutes of mercury electrodes in electrochemical stripping analysis of trace metals. The main advantage of these metals as electrode materials is their lower toxicity compared to mercury. Among the different configuration of bismuth, antimony and tin electrodes, one of the most attractive involves the modification of a support material with a bismuth, antimony or tin precursor compound (oxide, hydroxide or sparingly soluble salt). When the electrode is polarized to a sufficiently cathodic potential, the metal precursor is reduced to the respective metal which forms a thin %22film%22 on the surface of the support material. The present article is an overview of the existing state-of-the-art in the field of bismuth, antimony and tin precursor-modified sensors. This review covers and critically discusses the various fabrication approaches (support materials, types of precursor compounds, modification approaches, precursor reduction methods) and also lists typical applications of these precursor-modified sensors to electrochemical stripping analysis of metals.
dcterms:title
Electrodes Modified with Bismuth, Antimony and Tin Precursor Compounds for Electrochemical Stripping Analysis of Trace Metals. A Short Review Electrodes Modified with Bismuth, Antimony and Tin Precursor Compounds for Electrochemical Stripping Analysis of Trace Metals. A Short Review
skos:prefLabel
Electrodes Modified with Bismuth, Antimony and Tin Precursor Compounds for Electrochemical Stripping Analysis of Trace Metals. A Short Review Electrodes Modified with Bismuth, Antimony and Tin Precursor Compounds for Electrochemical Stripping Analysis of Trace Metals. A Short Review
skos:notation
RIV/00216208:11310/14:10218651!RIV15-MSM-11310___
n3:aktivita
n5:P n5:I
n3:aktivity
I, P(7AMB12GR003)
n3:dodaniDat
n16:2015
n3:domaciTvurceVysledku
n17:4454472
n3:druhVysledku
n9:O
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
14137
n3:idVysledku
RIV/00216208:11310/14:10218651
n3:jazykVysledku
n13:eng
n3:klicovaSlova
Trace metals.; Precursor compounds; Carbon paste electrodes; Screen-printed electrodes; Bismuth, tin, antimony electrodes
n3:klicoveSlovo
n6:Precursor%20compounds n6:Trace%20metals. n6:Screen-printed%20electrodes n6:Carbon%20paste%20electrodes n6:Bismuth n6:antimony%20electrodes n6:tin
n3:kontrolniKodProRIV
[A59CB834754A]
n3:obor
n14:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n4:7AMB12GR003
n3:rokUplatneniVysledku
n16:2014
n3:tvurceVysledku
Barek, Jiří Lesi, Nikolitsa Economou, Anastasios
n15:organizacniJednotka
11310