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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10209670%21RIV14-MSM-11310___
rdf:type
n10:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1021/cm402056j
dcterms:description
Electrochemical and chemical (with n-butyllithium) insertion of Li into TiO2 (anatase) is studied by Raman spectroscopy and by in situ Raman spectroelectrochemistry. Four isotopologue combinations in the system, namely (LixTiO2)-Li-6/7-O-16/18 (with x being the insertion coefficient), are prepared and studied. Spectral assignment is supported by numerical simulations using DFT calculations. The combination of experimental and theoretical Raman frequencies with the corresponding isotopic shifts brings new inputs for several still open questions about the Li-insertion into TiO2 (anatase). Electrochemical and chemical (with n-butyllithium) insertion of Li into TiO2 (anatase) is studied by Raman spectroscopy and by in situ Raman spectroelectrochemistry. Four isotopologue combinations in the system, namely (LixTiO2)-Li-6/7-O-16/18 (with x being the insertion coefficient), are prepared and studied. Spectral assignment is supported by numerical simulations using DFT calculations. The combination of experimental and theoretical Raman frequencies with the corresponding isotopic shifts brings new inputs for several still open questions about the Li-insertion into TiO2 (anatase).
dcterms:title
Lithium Insertion into Titanium Dioxide (Anatase): A Raman Study with O-16/18 and Li-6\7 Isotope Labeling Lithium Insertion into Titanium Dioxide (Anatase): A Raman Study with O-16/18 and Li-6\7 Isotope Labeling
skos:prefLabel
Lithium Insertion into Titanium Dioxide (Anatase): A Raman Study with O-16/18 and Li-6\7 Isotope Labeling Lithium Insertion into Titanium Dioxide (Anatase): A Raman Study with O-16/18 and Li-6\7 Isotope Labeling
skos:notation
RIV/00216208:11310/13:10209670!RIV14-MSM-11310___
n10:predkladatel
n16:orjk%3A11310
n3:aktivita
n15:I
n3:aktivity
I
n3:cisloPeriodika
18
n3:dodaniDat
n17:2014
n3:domaciTvurceVysledku
n13:9704418 n13:5876400 n13:5401070
n3:druhVysledku
n12:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
85135
n3:idVysledku
RIV/00216208:11310/13:10209670
n3:jazykVysledku
n18:eng
n3:klicovaSlova
spectroelectrochemistry; Raman spectroscopy; lithium insertion; titanium dioxide
n3:klicoveSlovo
n4:spectroelectrochemistry n4:titanium%20dioxide n4:Raman%20spectroscopy n4:lithium%20insertion
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[3D2A83870F9C]
n3:nazevZdroje
Chemistry of Materials
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
6
n3:rokUplatneniVysledku
n17:2013
n3:svazekPeriodika
25
n3:tvurceVysledku
Zukalová, Markéta Kavan, Ladislav Dračínský, Martin Frank, Otakar Bouša, Milan Lásková, Barbora
n3:wos
000330096600018
s:issn
0897-4756
s:numberOfPages
8
n7:doi
10.1021/cm402056j
n9:organizacniJednotka
11310