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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10159270%21RIV14-GA0-11310___
rdf:type
skos:Concept n19:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1016/j.tetasy.2013.02.008
dcterms:description
The highly enantioselective organocatalytic alpha-selenylation reaction of aldehydes using a hypervalent iodine compound as an oxidative agent from commercially available phenyl diselenide under mild oxidative conditions is described. This transformation affords alpha-selenyl aldehydes in good yields and with excellent enantioselectivities. By using hypervalent iodine compounds, it opens up a suitable and alternative way for the preparation of biologically active building blocks such as beta-hydroxy alcohols, alpha-amino acids, and alpha-hydroxy esters. The highly enantioselective organocatalytic alpha-selenylation reaction of aldehydes using a hypervalent iodine compound as an oxidative agent from commercially available phenyl diselenide under mild oxidative conditions is described. This transformation affords alpha-selenyl aldehydes in good yields and with excellent enantioselectivities. By using hypervalent iodine compounds, it opens up a suitable and alternative way for the preparation of biologically active building blocks such as beta-hydroxy alcohols, alpha-amino acids, and alpha-hydroxy esters.
dcterms:title
Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds
skos:prefLabel
Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds
skos:notation
RIV/00216208:11310/13:10159270!RIV14-GA0-11310___
n19:predkladatel
n20:orjk%3A11310
n4:aktivita
n5:I n5:P n5:Z
n4:aktivity
I, P(GAP207/10/0428), Z(MSM0021620857)
n4:cisloPeriodika
5-6
n4:dodaniDat
n16:2014
n4:domaciTvurceVysledku
n17:4633156 n17:5534305
n4:druhVysledku
n12:J
n4:duvernostUdaju
n14:S
n4:entitaPredkladatele
n10:predkladatel
n4:idSjednocenehoVysledku
77403
n4:idVysledku
RIV/00216208:11310/13:10159270
n4:jazykVysledku
n21:eng
n4:klicovaSlova
esters; selenenylation; organic-synthesis; selenium reagents; glutathione-peroxidase; organoselenium chemistry; alpha,beta-unsaturated aldehydes
n4:klicoveSlovo
n9:alpha n9:organoselenium%20chemistry n9:selenium%20reagents n9:glutathione-peroxidase n9:beta-unsaturated%20aldehydes n9:organic-synthesis n9:selenenylation n9:esters
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[EF95D5FD7DCA]
n4:nazevZdroje
Tetrahedron Asymmetry
n4:obor
n18:CC
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
2
n4:projekt
n7:GAP207%2F10%2F0428
n4:rokUplatneniVysledku
n16:2013
n4:svazekPeriodika
24
n4:tvurceVysledku
Veselý, Jan Kamlar, Martin
n4:wos
000316843000003
n4:zamer
n8:MSM0021620857
s:issn
0957-4166
s:numberOfPages
6
n22:doi
10.1016/j.tetasy.2013.02.008
n13:organizacniJednotka
11310