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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10159145%21RIV14-GA0-11310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.2174/1570179411310030008
dcterms:description
A highly enantioselectiveorganocatalyticnitromethylphenylsulfone addition to aliphatic alpha, beta-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the cyclic compounds in moderate yields, good diastereoselectivities and excellent enantioselectivities. A highly enantioselectiveorganocatalyticnitromethylphenylsulfone addition to aliphatic alpha, beta-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the cyclic compounds in moderate yields, good diastereoselectivities and excellent enantioselectivities.
dcterms:title
First Enantioselective Organocatalytic Addition of Nitromethylphenylsulfone to Enals. Enantioselective Synthesis of Cyclohexenones Bearing 3 Contiguousstereogeniccenters First Enantioselective Organocatalytic Addition of Nitromethylphenylsulfone to Enals. Enantioselective Synthesis of Cyclohexenones Bearing 3 Contiguousstereogeniccenters
skos:prefLabel
First Enantioselective Organocatalytic Addition of Nitromethylphenylsulfone to Enals. Enantioselective Synthesis of Cyclohexenones Bearing 3 Contiguousstereogeniccenters First Enantioselective Organocatalytic Addition of Nitromethylphenylsulfone to Enals. Enantioselective Synthesis of Cyclohexenones Bearing 3 Contiguousstereogeniccenters
skos:notation
RIV/00216208:11310/13:10159145!RIV14-GA0-11310___
n17:predkladatel
n18:orjk%3A11310
n3:aktivita
n10:P n10:I n10:Z
n3:aktivity
I, P(GAP207/10/0428), Z(MSM0021620857)
n3:cisloPeriodika
3
n3:dodaniDat
n12:2014
n3:domaciTvurceVysledku
n8:3157962 n8:7629338 n8:5534305
n3:druhVysledku
n5:J
n3:duvernostUdaju
n21:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
75174
n3:idVysledku
RIV/00216208:11310/13:10159145
n3:jazykVysledku
n16:eng
n3:klicovaSlova
cyclization; secondary amine; asymmetric synthesis; organocatalysis; enantioselective; cascade reaction
n3:klicoveSlovo
n4:asymmetric%20synthesis n4:cyclization n4:secondary%20amine n4:enantioselective n4:organocatalysis n4:cascade%20reaction
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[A7EEEFC9A59F]
n3:nazevZdroje
Current Organic Synthesis
n3:obor
n14:CC
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:projekt
n6:GAP207%2F10%2F0428
n3:rokUplatneniVysledku
n12:2013
n3:svazekPeriodika
10
n3:tvurceVysledku
Veselý, Jan Rios, Ramon Císařová, Ivana Hybelbauerová, Simona
n3:wos
000319444200008
n3:zamer
n15:MSM0021620857
s:issn
1570-1794
s:numberOfPages
5
n13:doi
10.2174/1570179411310030008
n22:organizacniJednotka
11310