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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10141577%21RIV14-MSM-11310___
rdf:type
skos:Concept n13:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1039/c2nj40724h
dcterms:description
A novel method enabling the synthesis of receptors based on the calix[4]arenes immobilized in the partial cone conformation is reported. The application of a protection/deprotection strategy using nosyl groups enables the regioselective introduction of functional groups (NO2 and NH2) into the upper rim of calix[4] arenes, leading finally to the substitution pattern so far inaccessible to calixarene chemistry. The introduction of two ureido functions at the para positions of the partial cone conformer yields a novel type of receptor which can bind anions even in a highly competitive solvent (DMSO). This revealed that the partial cone conformation, so far rather ignored in supramolecular chemistry, can be also very useful in design of novel anion receptors. A novel method enabling the synthesis of receptors based on the calix[4]arenes immobilized in the partial cone conformation is reported. The application of a protection/deprotection strategy using nosyl groups enables the regioselective introduction of functional groups (NO2 and NH2) into the upper rim of calix[4] arenes, leading finally to the substitution pattern so far inaccessible to calixarene chemistry. The introduction of two ureido functions at the para positions of the partial cone conformer yields a novel type of receptor which can bind anions even in a highly competitive solvent (DMSO). This revealed that the partial cone conformation, so far rather ignored in supramolecular chemistry, can be also very useful in design of novel anion receptors.
dcterms:title
Anion receptors based on ureidocalix[4]arenes immobilised in the partial cone conformation Anion receptors based on ureidocalix[4]arenes immobilised in the partial cone conformation
skos:prefLabel
Anion receptors based on ureidocalix[4]arenes immobilised in the partial cone conformation Anion receptors based on ureidocalix[4]arenes immobilised in the partial cone conformation
skos:notation
RIV/00216208:11310/13:10141577!RIV14-MSM-11310___
n13:predkladatel
n14:orjk%3A11310
n3:aktivita
n15:P n15:I
n3:aktivity
I, P(GA203/09/0691), P(IAAX08240901)
n3:cisloPeriodika
1
n3:dodaniDat
n7:2014
n3:domaciTvurceVysledku
n16:3157962
n3:druhVysledku
n10:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
61274
n3:idVysledku
RIV/00216208:11310/13:10141577
n3:jazykVysledku
n19:eng
n3:klicovaSlova
binding; chemistry; complexation; 1,3-alternate; recognition
n3:klicoveSlovo
n4:binding n4:chemistry n4:3-alternate n4:complexation n4:recognition n4:1
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[72B24BB142D8]
n3:nazevZdroje
New Journal of Chemistry
n3:obor
n20:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:projekt
n6:GA203%2F09%2F0691 n6:IAAX08240901
n3:rokUplatneniVysledku
n7:2013
n3:svazekPeriodika
37
n3:tvurceVysledku
Hudeček, Oldřich Lhoták, Pavel Budka, Jan Císařová, Ivana Cuřínová, Petra Dvořáková, Hana
n3:wos
000312485900026
s:issn
1144-0546
s:numberOfPages
8
n18:doi
10.1039/c2nj40724h
n21:organizacniJednotka
11310