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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10141574%21RIV14-MSM-11310___
rdf:type
skos:Concept n16:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1002/ejic.201300391
dcterms:description
Sunlight photolysis of decamethyltitanocene dihydrosulfide [Cp*2Ti(SH)2] (1, Cp* = 5-C5Me5) in toluene affords the titanium sulfide clusters [(Cp*Ti)6(3-S)8] (4) and [(Cp*Ti)4(3-S)3(2-S)3] (5), the former in very low yield and the latter in good yield. The crystal structures of both compounds are toluene solvates and are based on a nearly regular titanium octahedron for 4 and a trigonal pyramid for 5. The [(Cp*Ti)3(3-S)(2-S)3] (6) complex isolated in a trace amount from the photolysis of 1 in hexane could be a precursor of 4. A plausible mechanism for the formation of 5 and 6 follows a mechanism recently proposed for photolysis of [Cp*2Ti(OH)2] by U. Rosenthal et al. Sunlight photolysis of decamethyltitanocene dihydrosulfide [Cp*2Ti(SH)2] (1, Cp* = 5-C5Me5) in toluene affords the titanium sulfide clusters [(Cp*Ti)6(3-S)8] (4) and [(Cp*Ti)4(3-S)3(2-S)3] (5), the former in very low yield and the latter in good yield. The crystal structures of both compounds are toluene solvates and are based on a nearly regular titanium octahedron for 4 and a trigonal pyramid for 5. The [(Cp*Ti)3(3-S)(2-S)3] (6) complex isolated in a trace amount from the photolysis of 1 in hexane could be a precursor of 4. A plausible mechanism for the formation of 5 and 6 follows a mechanism recently proposed for photolysis of [Cp*2Ti(OH)2] by U. Rosenthal et al.
dcterms:title
Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6 Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6
skos:prefLabel
Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6 Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6
skos:notation
RIV/00216208:11310/13:10141574!RIV14-MSM-11310___
n16:predkladatel
n19:orjk%3A11310
n3:aktivita
n4:Z n4:I n4:P
n3:aktivity
I, P(GAP207/12/2368), Z(MSM0021620857)
n3:cisloPeriodika
19
n3:dodaniDat
n7:2014
n3:domaciTvurceVysledku
n12:3157962
n3:druhVysledku
n22:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
108995
n3:idVysledku
RIV/00216208:11310/13:10141574
n3:jazykVysledku
n20:eng
n3:klicovaSlova
sulfur; titanium; cluster compounds; cage compounds; metallocenes; photolysis
n3:klicoveSlovo
n8:metallocenes n8:cluster%20compounds n8:cage%20compounds n8:sulfur n8:photolysis n8:titanium
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[76232F4CA422]
n3:nazevZdroje
European Journal of Inorganic Chemistry
n3:obor
n17:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:projekt
n21:GAP207%2F12%2F2368
n3:rokUplatneniVysledku
n7:2013
n3:svazekPeriodika
neuveden
n3:tvurceVysledku
Císařová, Ivana Kubišta, Jiří Mach, Karel Horáček, Michal Pinkas, Jiří Gyepes, Róbert
n3:wos
000320783300007
n3:zamer
n18:MSM0021620857
s:issn
1434-1948
s:numberOfPages
7
n15:doi
10.1002/ejic.201300391
n13:organizacniJednotka
11310