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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10141573%21RIV14-GA0-11310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1016/j.jorganchem.2013.03.017
dcterms:description
Mononuclear silver and gold complexes [Ag(BzlCy)(Cl)] (1) and [Au(BzlCy)(Cl)] (2) were synthesized starting from the N-heterocyclic carbene (NHC) BzlCy center dot HCl (1,3-Dicyclohexylbenzimidazolium chloride) and characterized by NMR and ESI-MS spectral studies. Molecular structures of complexes [Ag(Bzl-Cy)(Cl)] (1) and [Au(BzlCy)(Cl)] (2.THF) were determined by X-ray crystallography. Formation of different species of these complexes 1 and 2 in gas phase was investigated by electrospray ionization mass spectrometry in positive mode and compared with solution formulation. To better understand the nature of NHC complexes and their reactivity with phenyl acetylene in gas phase, we synthesized a negatively charge tag gold complex [Au((S)BzlCy)(Cl)] starting from (S)BzlCy.HCl which prepared by the sulphonation of BzlCy. We investigated the formation of intermediate species [Au((S)BzlCy)(PhC C)] by the coordination of phenyl acetylene to the charge-tag gold complex in gas phase. We compared the stability of these NHC complexes and also investigated the decomposed mixture by electrospray ionization. Mononuclear silver and gold complexes [Ag(BzlCy)(Cl)] (1) and [Au(BzlCy)(Cl)] (2) were synthesized starting from the N-heterocyclic carbene (NHC) BzlCy center dot HCl (1,3-Dicyclohexylbenzimidazolium chloride) and characterized by NMR and ESI-MS spectral studies. Molecular structures of complexes [Ag(Bzl-Cy)(Cl)] (1) and [Au(BzlCy)(Cl)] (2.THF) were determined by X-ray crystallography. Formation of different species of these complexes 1 and 2 in gas phase was investigated by electrospray ionization mass spectrometry in positive mode and compared with solution formulation. To better understand the nature of NHC complexes and their reactivity with phenyl acetylene in gas phase, we synthesized a negatively charge tag gold complex [Au((S)BzlCy)(Cl)] starting from (S)BzlCy.HCl which prepared by the sulphonation of BzlCy. We investigated the formation of intermediate species [Au((S)BzlCy)(PhC C)] by the coordination of phenyl acetylene to the charge-tag gold complex in gas phase. We compared the stability of these NHC complexes and also investigated the decomposed mixture by electrospray ionization.
dcterms:title
Synthesis and characterization of silver and gold NHC complexes: Crystal structures and mass spectral studies Synthesis and characterization of silver and gold NHC complexes: Crystal structures and mass spectral studies
skos:prefLabel
Synthesis and characterization of silver and gold NHC complexes: Crystal structures and mass spectral studies Synthesis and characterization of silver and gold NHC complexes: Crystal structures and mass spectral studies
skos:notation
RIV/00216208:11310/13:10141573!RIV14-GA0-11310___
n17:predkladatel
n18:orjk%3A11310
n3:aktivita
n13:Z n13:P n13:I
n3:aktivity
I, P(GAP207/11/0338), Z(MSM0021620857)
n3:cisloPeriodika
July
n3:dodaniDat
n8:2014
n3:domaciTvurceVysledku
Kumar, Pramod n22:3157962
n3:druhVysledku
n16:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n21:predkladatel
n3:idSjednocenehoVysledku
109474
n3:idVysledku
RIV/00216208:11310/13:10141573
n3:jazykVysledku
n19:eng
n3:klicovaSlova
gold complex; silver complex; N-heterocyclic carbene; mass spectrometry; electrospray ionization
n3:klicoveSlovo
n7:mass%20spectrometry n7:gold%20complex n7:silver%20complex n7:electrospray%20ionization n7:N-heterocyclic%20carbene
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[1D44F3B078D6]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n11:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n20:GAP207%2F11%2F0338
n3:rokUplatneniVysledku
n8:2013
n3:svazekPeriodika
735
n3:tvurceVysledku
Kumar, Pramod Císařová, Ivana
n3:wos
000319195100005
n3:zamer
n15:MSM0021620857
s:issn
0022-328X
s:numberOfPages
6
n6:doi
10.1016/j.jorganchem.2013.03.017
n14:organizacniJednotka
11310