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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10134298%21RIV14-GA0-11310___
rdf:type
n7:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1016/j.micromeso.2013.03.023
dcterms:description
Zeolite UTL is the firstzeolite synthesized with intersecting 14- and 12-ring channels in the form of ger- manosilicate.Its framework consists of dense layers supported ('pillared')by D4R units enriched in Ge.The synthesis of UTL enabled anew insight into our understanding of zeolite properties,role of different templates,mechanism of zeolite synthesis,and isomorphous substitution.In addition to its attractive properties,zeolite UTL is the firstzeol ite that has been selectively transformed (dis-assembled)into indi- vidual 'UTL'layers with preservation of their structure.This disassembly is not only completely new ('top-down')approach in the modi ficationof zeolite materials but also enables further manipulation of the layers like swelling,pillaring,and stabilization.This resulted in anew family of UTL-bas ed materials.Upon suitable manipulation,the UTL layers can be condensed to form two new zeolites IPC-2 and IPC-4 (IZAcode PCR).These zeolites were synthesized via newly proposed synthetic mechanism ADOR (A-assembly,D-dis-assembly,O-organization,R-re-assembly).The ADOR app roach is believed to be ageneral strategy that will lead to the preparation of new zeolites. Zeolite UTL is the firstzeolite synthesized with intersecting 14- and 12-ring channels in the form of ger- manosilicate.Its framework consists of dense layers supported ('pillared')by D4R units enriched in Ge.The synthesis of UTL enabled anew insight into our understanding of zeolite properties,role of different templates,mechanism of zeolite synthesis,and isomorphous substitution.In addition to its attractive properties,zeolite UTL is the firstzeol ite that has been selectively transformed (dis-assembled)into indi- vidual 'UTL'layers with preservation of their structure.This disassembly is not only completely new ('top-down')approach in the modi ficationof zeolite materials but also enables further manipulation of the layers like swelling,pillaring,and stabilization.This resulted in anew family of UTL-bas ed materials.Upon suitable manipulation,the UTL layers can be condensed to form two new zeolites IPC-2 and IPC-4 (IZAcode PCR).These zeolites were synthesized via newly proposed synthetic mechanism ADOR (A-assembly,D-dis-assembly,O-organization,R-re-assembly).The ADOR app roach is believed to be ageneral strategy that will lead to the preparation of new zeolites.
dcterms:title
UTL zeolite and the way beyond UTL zeolite and the way beyond
skos:prefLabel
UTL zeolite and the way beyond UTL zeolite and the way beyond
skos:notation
RIV/00216208:11310/13:10134298!RIV14-GA0-11310___
n7:predkladatel
n13:orjk%3A11310
n3:aktivita
n5:P n5:I
n3:aktivity
I, P(GBP106/12/G015)
n3:cisloPeriodika
December
n3:dodaniDat
n4:2014
n3:domaciTvurceVysledku
n21:1747681
n3:druhVysledku
n6:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
113324
n3:idVysledku
RIV/00216208:11310/13:10134298
n3:jazykVysledku
n11:eng
n3:klicovaSlova
hydrolysis; synthesi; zeolite UTL
n3:klicoveSlovo
n8:hydrolysis n8:synthesi n8:zeolite%20UTL
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[C461C140B66E]
n3:nazevZdroje
Microporous and Mesoporous Materials
n3:obor
n10:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n15:GBP106%2F12%2FG015
n3:rokUplatneniVysledku
n4:2013
n3:svazekPeriodika
182
n3:tvurceVysledku
Shvets, Oleksiy V. Čejka, Jiří Nachtigall, Petr Roth, Wieslaw J.
n3:wos
000326058500028
s:issn
1387-1811
s:numberOfPages
10
n18:doi
10.1016/j.micromeso.2013.03.023
n20:organizacniJednotka
11310