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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F13%3A10133684%21RIV14-GA0-11310___
rdf:type
skos:Concept n12:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1021/ma302503w
dcterms:description
The electrostatic coassembly of a block copolymer polyelectrolyte poly(ethylene oxide-block-poly- (methacrylic acid), PEO705MINUS SIGN PMAA476, and oppositely charged surfactant, N-dodecylpyridinium chloride (DPCl), has been investigated by a combination of isothermal titration calorimetry (ITC), spin-echo NMR spectroscopy, and timeresolved SAXS measurements. The study (i) confirms the conclusions drawn from our earlier study [Macromolecules 2012, 45, 6474] by scattering and microscopy techniques (i.e., the ITC curves can be interpreted using arguments consistent with conclusions of the earlier study) and (ii) yields new insight into the thermodynamic and kinetic behavior of the self-assembling system. The most important finding obtained by stopped-flow time-resolved SAXS measurements concerns the surprisingly high rate of processes of creation of structurally ordered cores of self-assembled surfactantMINUS SIGN polyelectrolyte nanoparticles (<50 ms). The electrostatic coassembly of a block copolymer polyelectrolyte poly(ethylene oxide-block-poly- (methacrylic acid), PEO705MINUS SIGN PMAA476, and oppositely charged surfactant, N-dodecylpyridinium chloride (DPCl), has been investigated by a combination of isothermal titration calorimetry (ITC), spin-echo NMR spectroscopy, and timeresolved SAXS measurements. The study (i) confirms the conclusions drawn from our earlier study [Macromolecules 2012, 45, 6474] by scattering and microscopy techniques (i.e., the ITC curves can be interpreted using arguments consistent with conclusions of the earlier study) and (ii) yields new insight into the thermodynamic and kinetic behavior of the self-assembling system. The most important finding obtained by stopped-flow time-resolved SAXS measurements concerns the surprisingly high rate of processes of creation of structurally ordered cores of self-assembled surfactantMINUS SIGN polyelectrolyte nanoparticles (<50 ms).
dcterms:title
Thermodynamic and Kinetic Aspects of Coassembly of PEOMINUS SIGN PMAA Block Copolymer and DPCl Surfactants into Ordered Nanoparticles in Aqueous Solutions Studied by ITC, NMR, and Time-Resolved SAXS Techniques Thermodynamic and Kinetic Aspects of Coassembly of PEOMINUS SIGN PMAA Block Copolymer and DPCl Surfactants into Ordered Nanoparticles in Aqueous Solutions Studied by ITC, NMR, and Time-Resolved SAXS Techniques
skos:prefLabel
Thermodynamic and Kinetic Aspects of Coassembly of PEOMINUS SIGN PMAA Block Copolymer and DPCl Surfactants into Ordered Nanoparticles in Aqueous Solutions Studied by ITC, NMR, and Time-Resolved SAXS Techniques Thermodynamic and Kinetic Aspects of Coassembly of PEOMINUS SIGN PMAA Block Copolymer and DPCl Surfactants into Ordered Nanoparticles in Aqueous Solutions Studied by ITC, NMR, and Time-Resolved SAXS Techniques
skos:notation
RIV/00216208:11310/13:10133684!RIV14-GA0-11310___
n12:predkladatel
n13:orjk%3A11310
n3:aktivita
n4:P n4:Z n4:I
n3:aktivity
I, P(GAP106/12/0143), P(GAP208/10/0353), P(GCP205/11/J043), P(GPP208/12/P236), Z(MSM0021620857)
n3:cisloPeriodika
6
n3:dodaniDat
n19:2014
n3:domaciTvurceVysledku
n20:4637895 n20:3324923 n20:8039046 n20:6110568
n3:druhVysledku
n6:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
110943
n3:idVysledku
RIV/00216208:11310/13:10133684
n3:jazykVysledku
n21:eng
n3:klicovaSlova
soft matter; SAXS; isothermal titration calorimetry
n3:klicoveSlovo
n5:soft%20matter n5:isothermal%20titration%20calorimetry n5:SAXS
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[D262FB9D2C56]
n3:nazevZdroje
Macromolecules
n3:obor
n15:CD
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
8
n3:projekt
n18:GPP208%2F12%2FP236 n18:GAP208%2F10%2F0353 n18:GAP106%2F12%2F0143 n18:GCP205%2F11%2FJ043
n3:rokUplatneniVysledku
n19:2013
n3:svazekPeriodika
46
n3:tvurceVysledku
Angelov, Boris Gradzielski, Michal Procházka, Karel Tošner, Zdeněk Uchman, Mariusz Marcin Oh, Joongseok Chang, Taihyun Štěpánek, Miroslav
n3:wos
000316847500015
n3:zamer
n14:MSM0021620857
s:issn
0024-9297
s:numberOfPages
10
n22:doi
10.1021/ma302503w
n9:organizacniJednotka
11310