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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F12%3A10124603%21RIV13-GA0-11310___
rdf:type
skos:Concept n16:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1002/elan.201100616
dcterms:description
The performance of a microcrystalline boron-doped diamond electrode in a thin-layer and wall-jet amperometric detection cell for HPLC was compared with the spectrophotometric detection. Comparison of peak parameters of 2-, 3-, and 4-aminobiphenyl after their separation revealed satisfactory repeatabilities of signal responses for all detection modes and regarding electrochemical detection higher current densities and higher noise for the thin-layer arrangement, and a slightly wider linear dynamic range of calibration dependencies and lower quantitation limits in the 10-8 mol.L-1 concentration range for the wall-jet arrangement. This detection mode was further employed for the determination of studied aminobiphenyls in model samples of the synthetic colorant tartrazine. Using solid phase extraction for the preliminary separation and preconcentration of the analytes the limit of quantitation was lowered to nanomolar concentrations. The performance of a microcrystalline boron-doped diamond electrode in a thin-layer and wall-jet amperometric detection cell for HPLC was compared with the spectrophotometric detection. Comparison of peak parameters of 2-, 3-, and 4-aminobiphenyl after their separation revealed satisfactory repeatabilities of signal responses for all detection modes and regarding electrochemical detection higher current densities and higher noise for the thin-layer arrangement, and a slightly wider linear dynamic range of calibration dependencies and lower quantitation limits in the 10-8 mol.L-1 concentration range for the wall-jet arrangement. This detection mode was further employed for the determination of studied aminobiphenyls in model samples of the synthetic colorant tartrazine. Using solid phase extraction for the preliminary separation and preconcentration of the analytes the limit of quantitation was lowered to nanomolar concentrations.
dcterms:title
Thin-Layer and Wall-Jet Arrangement of Amperometric Detector with Boron-Doped Diamond Electrode: Comparison of Amperometric Determination of Aminobiphenyls in HPLC-ED Thin-Layer and Wall-Jet Arrangement of Amperometric Detector with Boron-Doped Diamond Electrode: Comparison of Amperometric Determination of Aminobiphenyls in HPLC-ED
skos:prefLabel
Thin-Layer and Wall-Jet Arrangement of Amperometric Detector with Boron-Doped Diamond Electrode: Comparison of Amperometric Determination of Aminobiphenyls in HPLC-ED Thin-Layer and Wall-Jet Arrangement of Amperometric Detector with Boron-Doped Diamond Electrode: Comparison of Amperometric Determination of Aminobiphenyls in HPLC-ED
skos:notation
RIV/00216208:11310/12:10124603!RIV13-GA0-11310___
n16:predkladatel
n17:orjk%3A11310
n5:aktivita
n12:Z n12:S n12:P n12:I
n5:aktivity
I, P(GBP206/12/G151), P(LC06035), P(ME10004), S, Z(MSM0021620857)
n5:cisloPeriodika
3
n5:dodaniDat
n15:2013
n5:domaciTvurceVysledku
n9:4454472 n9:3329194 n9:1623532
n5:druhVysledku
n22:J
n5:duvernostUdaju
n14:S
n5:entitaPredkladatele
n6:predkladatel
n5:idSjednocenehoVysledku
174353
n5:idVysledku
RIV/00216208:11310/12:10124603
n5:jazykVysledku
n20:eng
n5:klicovaSlova
liquid chromatography; dyes/pigments; boron-doped diamond; aminobiphenyls; amperometric detection
n5:klicoveSlovo
n7:liquid%20chromatography n7:boron-doped%20diamond n7:aminobiphenyls n7:amperometric%20detection n7:dyes%2Fpigments
n5:kodStatuVydavatele
DE - Spolková republika Německo
n5:kontrolniKodProRIV
[BD11F65AA110]
n5:nazevZdroje
Electroanalysis
n5:obor
n10:CG
n5:pocetDomacichTvurcuVysledku
3
n5:pocetTvurcuVysledku
3
n5:projekt
n13:GBP206%2F12%2FG151 n13:LC06035 n13:ME10004
n5:rokUplatneniVysledku
n15:2012
n5:svazekPeriodika
24
n5:tvurceVysledku
Pecková, Karolina Maixnerová, Lucie Barek, Jiří
n5:wos
000300931000025
n5:zamer
n8:MSM0021620857
s:issn
1040-0397
s:numberOfPages
10
n21:doi
10.1002/elan.201100616
n19:organizacniJednotka
11310