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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F12%3A10120354%21RIV13-GA0-11310___
rdf:type
n12:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1002/macp.201100509
dcterms:description
New stable polyacetylenes whose quantum yield of fluorescence is increased up to 62% because of the presence of pendant 4-(piperidine-1-yl)-1,8-naphtalimide groups are described. The polymers are prepared by two-step modification of copolymers of 1-(4-tert-butylphenyl)-6-chlorohex-1-yne and 1-phenylhex-1-yne consisting of the exchange of chlorine atoms at side groups for azide groups and subsequent Huisgen click reaction of the azide groups with ethynyl groups of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide. Modification is evidenced by 1H NMR, IR, Raman and UVvis spectroscopy. Modified polymers show the excitation energy transfer from their main chains on fluorophores and nearly preservation of fluorescence properties of fluorophores upon their binding to polymer chains. New stable polyacetylenes whose quantum yield of fluorescence is increased up to 62% because of the presence of pendant 4-(piperidine-1-yl)-1,8-naphtalimide groups are described. The polymers are prepared by two-step modification of copolymers of 1-(4-tert-butylphenyl)-6-chlorohex-1-yne and 1-phenylhex-1-yne consisting of the exchange of chlorine atoms at side groups for azide groups and subsequent Huisgen click reaction of the azide groups with ethynyl groups of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide. Modification is evidenced by 1H NMR, IR, Raman and UVvis spectroscopy. Modified polymers show the excitation energy transfer from their main chains on fluorophores and nearly preservation of fluorescence properties of fluorophores upon their binding to polymer chains.
dcterms:title
Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups
skos:prefLabel
Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups
skos:notation
RIV/00216208:11310/12:10120354!RIV13-GA0-11310___
n12:predkladatel
n13:orjk%3A11310
n3:aktivita
n19:I n19:P n19:Z
n3:aktivity
I, P(GA203/09/0803), P(GD203/08/H032), Z(MSM0021620857)
n3:cisloPeriodika
4
n3:dodaniDat
n16:2013
n3:domaciTvurceVysledku
n4:5069173 n4:9635939 n4:3128970 n4:4102274 n4:4994299 n4:1868047
n3:druhVysledku
n17:J
n3:duvernostUdaju
n21:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
159540
n3:idVysledku
RIV/00216208:11310/12:10120354
n3:jazykVysledku
n18:eng
n3:klicovaSlova
polymer modification; polyacetylenes; naphthalimide; fluorescence; click chemistry
n3:klicoveSlovo
n7:fluorescence n7:naphthalimide n7:click%20chemistry n7:polymer%20modification n7:polyacetylenes
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[0101AE9F9F03]
n3:nazevZdroje
Macromolecular Chemistry and Physics
n3:obor
n22:CD
n3:pocetDomacichTvurcuVysledku
6
n3:pocetTvurcuVysledku
6
n3:projekt
n9:GA203%2F09%2F0803 n9:GD203%2F08%2FH032
n3:rokUplatneniVysledku
n16:2012
n3:svazekPeriodika
213
n3:tvurceVysledku
Sivkova, Radoslava Parusheva Svoboda, Jan Zedník, Jiří Bláha, Michal Vohlídal, Jiří Sedláček, Jan
n3:wos
000300568900007
n3:zamer
n10:MSM0021620857
s:issn
1022-1352
s:numberOfPages
14
n20:doi
10.1002/macp.201100509
n6:organizacniJednotka
11310