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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F11%3A10104959%21RIV12-MSM-11310___
rdf:type
skos:Concept n12:Vysledek
dcterms:description
Boron doped diamond (BDD) has been recognized as nearly ideal electrode material for many electrochemical applications due to the low and stable background current over a wide potential range, corrosion and fouling resistance, high thermal conductivity, and high current densities. Microelectrodes and microelectrode arrays possess numerous attractive features for electrochemistry including reduced iR drop, low capacitive-charging currents, and steady-state diffusion currents. Coupling the advantages of the microelectrodes and their arrays with the usefulness of BDD is presented and discussed in this review on the examples of existing miniaturized BDD devices and their applications in organic electrochemistry. The varieties in their fabrication, construction, and applications in organic electrochemistry are presented. The latter include mainly electroanalysis, where single BDD microelectrodes have been employed as amperometric sensors in capillary electrophoretic techniques including electrophoretic microchips and other liquid flow systems, and further for in vivo/in vitro detection of biogenic compounds. Applications of BDD microelectrode arrays are rather limited, as their construction is a very challenging task and recent studies are more concerned with their fabrication and structural and electrochemical characterization. Thus, the techniques for the fabrication of such arrays and their construction are reviewed and their possibilities and limitations in organic electrochemistry based on existing results are discussed. Boron doped diamond (BDD) has been recognized as nearly ideal electrode material for many electrochemical applications due to the low and stable background current over a wide potential range, corrosion and fouling resistance, high thermal conductivity, and high current densities. Microelectrodes and microelectrode arrays possess numerous attractive features for electrochemistry including reduced iR drop, low capacitive-charging currents, and steady-state diffusion currents. Coupling the advantages of the microelectrodes and their arrays with the usefulness of BDD is presented and discussed in this review on the examples of existing miniaturized BDD devices and their applications in organic electrochemistry. The varieties in their fabrication, construction, and applications in organic electrochemistry are presented. The latter include mainly electroanalysis, where single BDD microelectrodes have been employed as amperometric sensors in capillary electrophoretic techniques including electrophoretic microchips and other liquid flow systems, and further for in vivo/in vitro detection of biogenic compounds. Applications of BDD microelectrode arrays are rather limited, as their construction is a very challenging task and recent studies are more concerned with their fabrication and structural and electrochemical characterization. Thus, the techniques for the fabrication of such arrays and their construction are reviewed and their possibilities and limitations in organic electrochemistry based on existing results are discussed.
dcterms:title
Boron doped diamond microelectrodes and microelectrode arrays in organic electrochemistry Boron doped diamond microelectrodes and microelectrode arrays in organic electrochemistry
skos:prefLabel
Boron doped diamond microelectrodes and microelectrode arrays in organic electrochemistry Boron doped diamond microelectrodes and microelectrode arrays in organic electrochemistry
skos:notation
RIV/00216208:11310/11:10104959!RIV12-MSM-11310___
n12:predkladatel
n13:orjk%3A11310
n3:aktivita
n10:P n10:Z
n3:aktivity
P(LC06035), Z(MSM0021620857)
n3:cisloPeriodika
17
n3:dodaniDat
n11:2012
n3:domaciTvurceVysledku
n18:1623532 n18:4454472
n3:druhVysledku
n15:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
188639
n3:idVysledku
RIV/00216208:11310/11:10104959
n3:jazykVysledku
n7:eng
n3:klicovaSlova
Voltammetry; Review; Organic compounds; Microelectrode array; Microelectrode; In vivo/in vitro measurements; Boron doped diamond; Amperometry
n3:klicoveSlovo
n5:Review n5:Boron%20doped%20diamond n5:Amperometry n5:Microelectrode n5:Microelectrode%20array n5:In%20vivo%2Fin%20vitro%20measurements n5:Organic%20compounds n5:Voltammetry
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[DA3366C6B0B4]
n3:nazevZdroje
Current Organic Chemistry
n3:obor
n20:CG
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n19:LC06035
n3:rokUplatneniVysledku
n11:2011
n3:svazekPeriodika
15
n3:tvurceVysledku
Pecková, Karolina Barek, Jiří
n3:wos
000294899100009
n3:zamer
n6:MSM0021620857
s:issn
1385-2728
s:numberOfPages
15
n16:organizacniJednotka
11310