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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F11%3A10101066%21RIV12-MSM-11310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1016/j.jorganchem.2011.08.043
dcterms:description
Two polar phosphinoferrocene ligands, 1'-(diphenylphosphino)ferrocene-1-carboxamide (1) and 1'-(diphenylphosphino)ferrocene-1-carbohydrazide (2), were synthesized in good yields from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) via the reactive benzotriazole derivative, 1-[1'-(diphenylphosphino)ferrocene-1-carbonyl]-1H-1,2,3-benzotriazole (3). The hydrazide was further converted via standard condensation reactions to three phosphinoferrocene heterocycles, viz 2-[1'-(diphenylphosphino)ferrocen-1-yl]-1,3,4-oxadiazole (4), 1-[1'-(diphenylphosphino)ferrocen-1-carbonyl]-3,5-dimethyl-1,2-pyrazole (5), and 1-[1'-(diphenylphosphino)ferrocene-1-carboxamido]-3,5-dimethylpyrrole (6). These compounds have been structurally characterized and studied as ligands in palladium(II) complexes. Two polar phosphinoferrocene ligands, 1'-(diphenylphosphino)ferrocene-1-carboxamide (1) and 1'-(diphenylphosphino)ferrocene-1-carbohydrazide (2), were synthesized in good yields from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) via the reactive benzotriazole derivative, 1-[1'-(diphenylphosphino)ferrocene-1-carbonyl]-1H-1,2,3-benzotriazole (3). The hydrazide was further converted via standard condensation reactions to three phosphinoferrocene heterocycles, viz 2-[1'-(diphenylphosphino)ferrocen-1-yl]-1,3,4-oxadiazole (4), 1-[1'-(diphenylphosphino)ferrocen-1-carbonyl]-3,5-dimethyl-1,2-pyrazole (5), and 1-[1'-(diphenylphosphino)ferrocene-1-carboxamido]-3,5-dimethylpyrrole (6). These compounds have been structurally characterized and studied as ligands in palladium(II) complexes.
dcterms:title
Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands
skos:prefLabel
Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands Synthesis and structural characterization of 1'-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands
skos:notation
RIV/00216208:11310/11:10101066!RIV12-MSM-11310___
n17:predkladatel
n21:orjk%3A11310
n3:aktivita
n15:S n15:Z
n3:aktivity
S, Z(MSM0021620857)
n3:cisloPeriodika
23
n3:dodaniDat
n8:2012
n3:domaciTvurceVysledku
n11:5448220 n11:8116997 n11:3157962
n3:druhVysledku
n16:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
233885
n3:idVysledku
RIV/00216208:11310/11:10101066
n3:jazykVysledku
n12:eng
n3:klicovaSlova
Structure elucidation; Palladium complexes; Heterocycles; Hydrazides; Amides; Phosphines; Ferrocene
n3:klicoveSlovo
n7:Heterocycles n7:Structure%20elucidation n7:Palladium%20complexes n7:Amides n7:Hydrazides n7:Ferrocene n7:Phosphines
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[63DC6C17B6C1]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n18:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n8:2011
n3:svazekPeriodika
696
n3:tvurceVysledku
Štěpnička, Petr Císařová, Ivana Solařová, Hana
n3:wos
000296551400021
n3:zamer
n20:MSM0021620857
s:issn
0022-328X
s:numberOfPages
14
n13:doi
10.1016/j.jorganchem.2011.08.043
n14:organizacniJednotka
11310