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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F11%3A10099641%21RIV12-MSM-11310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.1107/S160053681103621X
dcterms:description
The molecular geometry of the complex cation in the title structure, [(mu-Cl)(3){Ru(II)(eta(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) salt [Pandey et al. (1999). J. Organomet. Chem. 592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetrahedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) angstrom and 107.10 (3)-110.56 (3)degrees, respectively. There are no significant intermolecular interactions in the crystal except for some weak C-H...Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic interactions between the ionic constituents. The molecular geometry of the complex cation in the title structure, [(mu-Cl)(3){Ru(II)(eta(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) salt [Pandey et al. (1999). J. Organomet. Chem. 592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetrahedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) angstrom and 107.10 (3)-110.56 (3)degrees, respectively. There are no significant intermolecular interactions in the crystal except for some weak C-H...Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic interactions between the ionic constituents.
dcterms:title
Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)
skos:prefLabel
Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)
skos:notation
RIV/00216208:11310/11:10099641!RIV12-MSM-11310___
n17:predkladatel
n21:orjk%3A11310
n3:aktivita
n7:S n7:Z
n3:aktivity
S, Z(MSM0021620857)
n3:cisloPeriodika
10
n3:dodaniDat
n10:2012
n3:domaciTvurceVysledku
n11:3157962 n11:8116997 n11:9177590
n3:druhVysledku
n12:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
236100
n3:idVysledku
RIV/00216208:11310/11:10099641
n3:jazykVysledku
n20:eng
n3:klicovaSlova
Structure elucidation; Iron complexes; Arene-ruthenium complexes
n3:klicoveSlovo
n4:Structure%20elucidation n4:Arene-ruthenium%20complexes n4:Iron%20complexes
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[EA0FE9C5A85F]
n3:nazevZdroje
Acta Crystallographica Section E: Structure Reports Online
n3:obor
n19:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n10:2011
n3:svazekPeriodika
67
n3:tvurceVysledku
Schulz, Jiří Štěpnička, Petr Císařová, Ivana
n3:wos
000295614800040
n3:zamer
n9:MSM0021620857
s:issn
1600-5368
s:numberOfPages
2
n18:doi
10.1107/S160053681103621X
n14:organizacniJednotka
11310