This HTML5 document contains 53 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n6http://localhost/temp/predkladatel/
n16http://linked.opendata.cz/resource/domain/vavai/projekt/
n4http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n18http://linked.opendata.cz/resource/domain/vavai/subjekt/
n17http://linked.opendata.cz/ontology/domain/vavai/
n21http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n20http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n11http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216208%3A11310%2F11%3A10099392%21RIV12-GA0-11310___/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n19http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n7http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F11%3A10099392%21RIV12-GA0-11310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Two novel methods for determination of binding constants in the systems with borate and cyclodextrin complexation were developed. The methods enable to determine all binding parameters in these systems and even the binding constants of interaction of a neutral analyte with a neutral cyclodextrin. The first method is based on nonlinear fitting of experimental data and further evaluation of fitting parameters. The second method requires a multiple regression. The methods provide identical results with low experimental error. Only one set of measurements is required for both methods. Thus the binding parameters can be mutually compared. The binding parameters for neutral analytes ((R,R)-(+)-hydrobenzoin and (S,S)-(-)-hydrobenzoin) and neutral cyclodextrin (heptakis(2,6-di-O-methyl)-beta-cyclodextrin) were evaluated and the effect of individual types of interaction was revealed. Two novel methods for determination of binding constants in the systems with borate and cyclodextrin complexation were developed. The methods enable to determine all binding parameters in these systems and even the binding constants of interaction of a neutral analyte with a neutral cyclodextrin. The first method is based on nonlinear fitting of experimental data and further evaluation of fitting parameters. The second method requires a multiple regression. The methods provide identical results with low experimental error. Only one set of measurements is required for both methods. Thus the binding parameters can be mutually compared. The binding parameters for neutral analytes ((R,R)-(+)-hydrobenzoin and (S,S)-(-)-hydrobenzoin) and neutral cyclodextrin (heptakis(2,6-di-O-methyl)-beta-cyclodextrin) were evaluated and the effect of individual types of interaction was revealed.
dcterms:title
Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation
skos:prefLabel
Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation
skos:notation
RIV/00216208:11310/11:10099392!RIV12-GA0-11310___
n17:predkladatel
n18:orjk%3A11310
n3:aktivita
n12:Z n12:S n12:P
n3:aktivity
P(GA203/08/1428), S, Z(MSM0021620857)
n3:cisloPeriodika
40
n3:dodaniDat
n7:2012
n3:domaciTvurceVysledku
n4:5129680 n4:3899896 n4:5263344 n4:5301386 n4:2664755
n3:druhVysledku
n13:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
211810
n3:idVysledku
RIV/00216208:11310/11:10099392
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Electrophoresis; Binding constants; Complexation; Cyclodextrin; Borate complexation
n3:klicoveSlovo
n10:Borate%20complexation n10:Cyclodextrin n10:Complexation n10:Binding%20constants n10:Electrophoresis
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[8A25726B9FEE]
n3:nazevZdroje
Journal of Chromatography A
n3:obor
n15:CB
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n16:GA203%2F08%2F1428
n3:rokUplatneniVysledku
n7:2011
n3:svazekPeriodika
1218
n3:tvurceVysledku
Dubský, Pavel Tesařová, Eva Gaš, Bohuslav Beneš, Martin Svobodová, Jana
n3:wos
000295300600017
n3:zamer
n21:MSM0021620857
s:issn
0021-9673
s:numberOfPages
8
n20:doi
10.1016/j.chroma.2011.07.088
n6:organizacniJednotka
11310