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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F10%3A10081686%21RIV11-MSM-11310___
rdf:type
skos:Concept n15:Vysledek
dcterms:description
The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time. The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time.
dcterms:title
Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O
skos:prefLabel
Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O
skos:notation
RIV/00216208:11310/10:10081686!RIV11-MSM-11310___
n3:aktivita
n16:V
n3:aktivity
V
n3:cisloPeriodika
11
n3:dodaniDat
n12:2011
n3:domaciTvurceVysledku
n6:5347440
n3:druhVysledku
n13:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
291566
n3:idVysledku
RIV/00216208:11310/10:10081686
n3:jazykVysledku
n11:eng
n3:klicovaSlova
EPR; X-ray structure; Copper (II); Glycinato complex; Decavanadate
n3:klicoveSlovo
n7:Copper%20%28II%29 n7:Decavanadate n7:Glycinato%20complex n7:X-ray%20structure n7:EPR
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[3736946D05AD]
n3:nazevZdroje
Inorganic Chemistry Communication
n3:obor
n9:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n12:2010
n3:svazekPeriodika
13
n3:tvurceVysledku
Plesch, Gustav Rakovský, Erik Gyepes, Róbert Schwendt, Peter Klištincová, Lenka
n3:wos
000282867800012
s:issn
1387-7003
s:numberOfPages
3
n8:organizacniJednotka
11310