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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F10%3A10070155%21RIV11-GA0-11310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
An organocatalytic, highly enantioselective addition of 1- fluoro-1-nitro(phenylsulfonyl)methane to alfa,beta-unsaturated aldehydes is reported. The reaction is simply catalyzed by secondary amines and furnishes the corresponding fluorinated derivatives in good yields, with moderate diastereoselectivities and excellent enantioselectivities. An organocatalytic, highly enantioselective addition of 1- fluoro-1-nitro(phenylsulfonyl)methane to alfa,beta-unsaturated aldehydes is reported. The reaction is simply catalyzed by secondary amines and furnishes the corresponding fluorinated derivatives in good yields, with moderate diastereoselectivities and excellent enantioselectivities.
dcterms:title
Highly Enantioselective Addition of 1-Fluoro-1-nitro(phenylsulfonyl)methane to alpha,beta-Unsaturated Aldehydes Highly Enantioselective Addition of 1-Fluoro-1-nitro(phenylsulfonyl)methane to alpha,beta-Unsaturated Aldehydes
skos:prefLabel
Highly Enantioselective Addition of 1-Fluoro-1-nitro(phenylsulfonyl)methane to alpha,beta-Unsaturated Aldehydes Highly Enantioselective Addition of 1-Fluoro-1-nitro(phenylsulfonyl)methane to alpha,beta-Unsaturated Aldehydes
skos:notation
RIV/00216208:11310/10:10070155!RIV11-GA0-11310___
n3:aktivita
n5:Z n5:P
n3:aktivity
P(GP203/09/P193), Z(MSM0021620857)
n3:cisloPeriodika
28
n3:dodaniDat
n17:2011
n3:domaciTvurceVysledku
n11:5534305 n11:4633156 n11:3157962 n11:7629338
n3:druhVysledku
n12:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
261578
n3:idVysledku
RIV/00216208:11310/10:10070155
n3:jazykVysledku
n15:eng
n3:klicovaSlova
Michael addition; Diastereoselectivity; Enantioselectivity; Aldehydes; Organocatalysis; Fluorine
n3:klicoveSlovo
n8:Michael%20addition n8:Diastereoselectivity n8:Enantioselectivity n8:Aldehydes n8:Organocatalysis n8:Fluorine
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[77CC88C19E2B]
n3:nazevZdroje
European Journal of Organic Chemistry
n3:obor
n4:CC
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
8
n3:projekt
n16:GP203%2F09%2FP193
n3:rokUplatneniVysledku
n17:2010
n3:svazekPeriodika
2010
n3:tvurceVysledku
Rios, Ramon Císařová, Ivana Alba, Andrea-Nekane R. Bravo, Natalia Hybelbauerová, Simona Kamlar, Martin Moyano, Albert Veselý, Jan
n3:wos
000283387900017
n3:zamer
n18:MSM0021620857
s:issn
1434-193X
s:numberOfPages
7
n6:organizacniJednotka
11310