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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F10%3A10057164%21RIV11-MSM-11310___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. During the reduction in the presence of ethylene, a new tetramethyl(perfluoroalkyl)-eta-4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction. Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. During the reduction in the presence of ethylene, a new tetramethyl(perfluoroalkyl)-eta-4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction.
dcterms:title
Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2]
skos:prefLabel
Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2]
skos:notation
RIV/00216208:11310/10:10057164!RIV11-MSM-11310___
n3:aktivita
n10:Z n10:S n10:P
n3:aktivity
P(IAA4072203), P(LC06070), S, Z(AV0Z40720504)
n3:cisloPeriodika
3
n3:dodaniDat
n13:2011
n3:domaciTvurceVysledku
n8:3157962 n8:7586760
n3:druhVysledku
n17:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
292565
n3:idVysledku
RIV/00216208:11310/10:10057164
n3:jazykVysledku
n4:eng
n3:klicovaSlova
alkene complexes; rhodium complexes; fluorous cyclopentadienes
n3:klicoveSlovo
n7:rhodium%20complexes n7:fluorous%20cyclopentadienes n7:alkene%20complexes
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[7373D2E7C432]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
7
n3:projekt
n6:IAA4072203 n6:LC06070
n3:rokUplatneniVysledku
n13:2010
n3:svazekPeriodika
695
n3:tvurceVysledku
Krupková, Alena Zámrzla, Milan Čermák, Jan Thi, Thu Huong Nguyen Auerová, Kateřina Vojtíšek, Pavel Císařová, Ivana
n3:wos
000273782000010
n3:zamer
n18:AV0Z40720504
s:issn
0022-328X
s:numberOfPages
7
n11:organizacniJednotka
11310