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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F10%3A10057086%21RIV11-MSM-11310___
rdf:type
skos:Concept n18:Vysledek
dcterms:description
In this communication, we report the synthesis and crystallographic characterization of a rare molecular linear trimer composed of Ca2+ and a carboxyphosphonate (hydroxyphosphonoacetate, HPAA), namely Ca-3(HPAA)(2)(H2O)(14). The two HPAA(3-) ligands function as bridges between the three Ca2+ ions. The central Ca2+ center is found in an octahedral environment, whereas the peripheral Ca2+ centers are in an 8-coordinated environment. This Ca-3(HPAA)(2)(H2O)(14) trimer was found to be an effective corrosion inhibitor for carbon steel surfaces at pH 7.3. Furthermore, we have proven by a variety of techniques that the identity of the anticorrosion film is the same as the rationally synthesized Ca-3(HPAA)(2)(H2O)(14). In this communication, we report the synthesis and crystallographic characterization of a rare molecular linear trimer composed of Ca2+ and a carboxyphosphonate (hydroxyphosphonoacetate, HPAA), namely Ca-3(HPAA)(2)(H2O)(14). The two HPAA(3-) ligands function as bridges between the three Ca2+ ions. The central Ca2+ center is found in an octahedral environment, whereas the peripheral Ca2+ centers are in an 8-coordinated environment. This Ca-3(HPAA)(2)(H2O)(14) trimer was found to be an effective corrosion inhibitor for carbon steel surfaces at pH 7.3. Furthermore, we have proven by a variety of techniques that the identity of the anticorrosion film is the same as the rationally synthesized Ca-3(HPAA)(2)(H2O)(14).
dcterms:title
Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion
skos:prefLabel
Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion
skos:notation
RIV/00216208:11310/10:10057086!RIV11-MSM-11310___
n3:aktivita
n12:Z
n3:aktivity
Z(MSM0021620857)
n3:cisloPeriodika
7
n3:dodaniDat
n13:2011
n3:domaciTvurceVysledku
n17:3157962
n3:druhVysledku
n8:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
287557
n3:idVysledku
RIV/00216208:11310/10:10057086
n3:jazykVysledku
n9:eng
n3:klicovaSlova
3D; 1D; hybrids; surfaces; frameworks; dissolution; osteocalcin; phosphonates; inhibition
n3:klicoveSlovo
n4:phosphonates n4:1D n4:hybrids n4:frameworks n4:surfaces n4:inhibition n4:dissolution n4:osteocalcin n4:3D
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[BC0C979F0FDC]
n3:nazevZdroje
ACS Applied Materials & Interfaces
n3:obor
n16:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n13:2010
n3:svazekPeriodika
2
n3:tvurceVysledku
Demadis, Konstantinos Papadaki, Maria Císařová, Ivana
n3:wos
000280367000007
n3:zamer
n6:MSM0021620857
s:issn
1944-8244
s:numberOfPages
3
n14:organizacniJednotka
11310