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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F09%3A10001118%21RIV10-GA0-11310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
The stannylene {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn (1) did not react with CO2 at room temperature and atmospheric pressure, but its oxidation product {[2-[(CH3)(2)NCH2](2)C6H4](2)Sn-(mu-O)}(2) (2) is very reactive toward CO2 to give the cyclic compound {[2-[(CH3)(2)NCH2](2)C6H4}(2)Sn](2)(mu-O)(mu-CO3) (2b). The product of reaction of 2 with silicon grease is also a cyclic compound with an eight-membered ring, {{{2-[(CH3)(2)NCH2](2)C6H4}(2)Sn}(Me2SiO)}(2) (2c), as the structural characterization revealed (XRD). Triphenylsilanol condensates with 2 to form {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn(OSiPh3)(2) (2b). The reaction of 2 with ethylene glycol gave the cyclic compound {2-[(CH3)(2)-NCH2](2)C6H4}(2)Sn(OCH2CH2O) center dot 1/2(HOCH2CH2OH)(2e). The stannylene {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn (1) did not react with CO2 at room temperature and atmospheric pressure, but its oxidation product {[2-[(CH3)(2)NCH2](2)C6H4](2)Sn-(mu-O)}(2) (2) is very reactive toward CO2 to give the cyclic compound {[2-[(CH3)(2)NCH2](2)C6H4}(2)Sn](2)(mu-O)(mu-CO3) (2b). The product of reaction of 2 with silicon grease is also a cyclic compound with an eight-membered ring, {{{2-[(CH3)(2)NCH2](2)C6H4}(2)Sn}(Me2SiO)}(2) (2c), as the structural characterization revealed (XRD). Triphenylsilanol condensates with 2 to form {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn(OSiPh3)(2) (2b). The reaction of 2 with ethylene glycol gave the cyclic compound {2-[(CH3)(2)-NCH2](2)C6H4}(2)Sn(OCH2CH2O) center dot 1/2(HOCH2CH2OH)(2e).
dcterms:title
Reactivity of a C,N-Chelated Stannoxane Reactivity of a C,N-Chelated Stannoxane
skos:prefLabel
Reactivity of a C,N-Chelated Stannoxane Reactivity of a C,N-Chelated Stannoxane
skos:notation
RIV/00216208:11310/09:10001118!RIV10-GA0-11310___
n3:aktivita
n10:P n10:Z
n3:aktivity
P(GA104/09/0829), P(GA203/07/0468), Z(MSM0021627501)
n3:cisloPeriodika
8
n3:dodaniDat
n18:2010
n3:domaciTvurceVysledku
n8:3157962
n3:druhVysledku
n13:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
338211
n3:idVysledku
RIV/00216208:11310/09:10001118
n3:jazykVysledku
n6:eng
n3:klicovaSlova
Reactivity; C,N-Chelated; Stannoxane
n3:klicoveSlovo
n7:N-Chelated n7:C n7:Reactivity n7:Stannoxane
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[546D2F30A5D5]
n3:nazevZdroje
Organometallics
n3:obor
n11:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
7
n3:projekt
n17:GA104%2F09%2F0829 n17:GA203%2F07%2F0468
n3:rokUplatneniVysledku
n18:2009
n3:svazekPeriodika
28
n3:tvurceVysledku
Císařová, Ivana Zevaco, Thomas Walter, Olaf Padělková, Zdeňka Růžička, Aleš Vaňkátová, Hana Nechaev, Mikhail
n3:wos
000265383700034
n3:zamer
n12:MSM0021627501
s:issn
0276-7333
s:numberOfPages
4
n9:organizacniJednotka
11310