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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F09%3A10001113%21RIV10-GA0-11310___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7). The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7).
dcterms:title
Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives
skos:prefLabel
Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives
skos:notation
RIV/00216208:11310/09:10001113!RIV10-GA0-11310___
n3:aktivita
n13:Z n13:P
n3:aktivity
P(GA203/07/0468), P(KJB401550802), Z(MSM0021627501)
n3:cisloPeriodika
10
n3:dodaniDat
n7:2010
n3:domaciTvurceVysledku
n10:3157962
n3:druhVysledku
n15:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
338196
n3:idVysledku
RIV/00216208:11310/09:10001113
n3:jazykVysledku
n17:eng
n3:klicovaSlova
CNchelatedTin(II); Lead(II)Compounds; ZirconoceneDichlorideDerivatives
n3:klicoveSlovo
n9:Lead%28II%29Compounds n9:CNchelatedTin%28II%29 n9:ZirconoceneDichlorideDerivatives
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[96DCB0F1FE62]
n3:nazevZdroje
Organometallics
n3:obor
n6:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
7
n3:projekt
n14:GA203%2F07%2F0468 n14:KJB401550802
n3:rokUplatneniVysledku
n7:2009
n3:svazekPeriodika
28
n3:tvurceVysledku
Císařová, Ivana Padělková, Zdeňka Bareš, Josef Růžička, Aleš Černošek, Zdeněk Philippe, Philippe Pirio, Nadine
n3:wos
000266156900023
n3:zamer
n11:MSM0021627501
s:issn
0276-7333
s:numberOfPages
4
n19:organizacniJednotka
11310