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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F09%3A10001105%21RIV10-GA0-11310___
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Triorganotin(IV) hydrides and cyclopentadienides as well as hexaorganodistannanes containing the moiety L-CN (2-(N,N-dimethylaminomethyl)phenyl-) as chelating ligand and phenyl, n-butyl or t-butyl substituents were prepared and characterized by NMR and XRD. The compounds reveal trigonal bipyramidal geometry around the central tin atom except for the distannanes in which the tin atom has tetrahedral configuration. The di-n-butyl distannane cannot be oxidized by oxygen or heavier chalcogens and give no tin radical when irradiated by UV light or treated with the TEMPO - free radical at room temperature. L-CN(t-Bu)(2)SnH undergoes reaction in solution toward the corresponding distannane. The hydrostannation reaction of L-CN(n-Bu)(2)SnH with ferrocenylacetylene was investigated. The CO2 activation by L-CN(n-Bu)(2)SnH was also examined. Triorganotin(IV) hydrides and cyclopentadienides as well as hexaorganodistannanes containing the moiety L-CN (2-(N,N-dimethylaminomethyl)phenyl-) as chelating ligand and phenyl, n-butyl or t-butyl substituents were prepared and characterized by NMR and XRD. The compounds reveal trigonal bipyramidal geometry around the central tin atom except for the distannanes in which the tin atom has tetrahedral configuration. The di-n-butyl distannane cannot be oxidized by oxygen or heavier chalcogens and give no tin radical when irradiated by UV light or treated with the TEMPO - free radical at room temperature. L-CN(t-Bu)(2)SnH undergoes reaction in solution toward the corresponding distannane. The hydrostannation reaction of L-CN(n-Bu)(2)SnH with ferrocenylacetylene was investigated. The CO2 activation by L-CN(n-Bu)(2)SnH was also examined.
dcterms:title
C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides
skos:prefLabel
C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides
skos:notation
RIV/00216208:11310/09:10001105!RIV10-GA0-11310___
n3:aktivita
n8:Z n8:P
n3:aktivity
P(GA104/09/0829), P(KJB401550802), Z(MSM0021627501)
n3:cisloPeriodika
18
n3:dodaniDat
n6:2010
n3:domaciTvurceVysledku
n14:3157962
n3:druhVysledku
n19:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
307366
n3:idVysledku
RIV/00216208:11310/09:10001105
n3:jazykVysledku
n13:eng
n3:klicovaSlova
tin
n3:klicoveSlovo
n4:tin
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[BA5B30F267D7]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n18:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
8
n3:projekt
n12:KJB401550802 n12:GA104%2F09%2F0829
n3:rokUplatneniVysledku
n6:2009
n3:svazekPeriodika
694
n3:tvurceVysledku
Černošek, Zdeněk Lyčka, Antonín Padělková, Zdeňka Nechaev, Mikhail Turek, Jan Růžička, Aleš Císařová, Ivana Erben, Milan
n3:wos
000268265200020
n3:zamer
n16:MSM0021627501
s:issn
0022-328X
s:numberOfPages
7
n17:organizacniJednotka
11310