This HTML5 document contains 48 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n17http://localhost/temp/predkladatel/
n15http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n7http://linked.opendata.cz/ontology/domain/vavai/
n6http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
n4http://linked.opendata.cz/ontology/domain/vavai/riv/
skoshttp://www.w3.org/2004/02/skos/core#
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n5http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n16http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n18http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216208%3A11310%2F09%3A10000304%21RIV11-MSM-11310___/
n13http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F09%3A10000304%21RIV11-MSM-11310___
rdf:type
skos:Concept n7:Vysledek
dcterms:description
Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position. Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position.
dcterms:title
Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)
skos:prefLabel
Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)
skos:notation
RIV/00216208:11310/09:10000304!RIV11-MSM-11310___
n4:aktivita
n10:Z
n4:aktivity
Z(MSM0021620857)
n4:cisloPeriodika
33
n4:dodaniDat
n13:2011
n4:domaciTvurceVysledku
n15:5347440
n4:druhVysledku
n12:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n18:predkladatel
n4:idSjednocenehoVysledku
314187
n4:idVysledku
RIV/00216208:11310/09:10000304
n4:jazykVysledku
n16:eng
n4:klicovaSlova
stereochemistry; ligands; mandelic-acid; peroxo complexes; peroxovanadium complexes; supramolecular interactions; vanadium(v) oxo; coordination polymers; crystal-structure; Oxo-monoperoxo complexes
n4:klicoveSlovo
n5:Oxo-monoperoxo%20complexes n5:stereochemistry n5:coordination%20polymers n5:ligands n5:vanadium%28v%29%20oxo n5:mandelic-acid n5:crystal-structure n5:peroxo%20complexes n5:peroxovanadium%20complexes n5:supramolecular%20interactions
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[8EAD0648BCBF]
n4:nazevZdroje
New Journal of Chemistry
n4:obor
n14:CA
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
4
n4:rokUplatneniVysledku
n13:2009
n4:svazekPeriodika
2009
n4:tvurceVysledku
Sivák, Michal Tatiersky, Jozef Pacigová, Silvia Gyepes, Róbert
n4:wos
000267728200012
n4:zamer
n6:MSM0021620857
s:issn
1144-0546
s:numberOfPages
8
n17:organizacniJednotka
11310