This HTML5 document contains 52 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n10http://localhost/temp/predkladatel/
n14http://linked.opendata.cz/resource/domain/vavai/projekt/
n5http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n12http://linked.opendata.cz/ontology/domain/vavai/
n18http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n16http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216208%3A11310%2F09%3A10000118%21RIV10-GA0-11310___/
n7http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n19http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n4http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F09%3A10000118%21RIV10-GA0-11310___
rdf:type
n12:Vysledek skos:Concept
dcterms:description
Intramolecular structures in amphiphilic graft copolymers with hydrophilic side chains and hydrophobic backbone have been studied by molecular dynamics simulations. We have found that balance of repulsive and attractive intramolecular interactions may result in the pearl-necklace-type conformations. The globular ?pearls? are formed by collapsed segments of the main chain comprising multiple spacers; these pearls are stabilized against aggregation by repulsive interactions of the hydrophilic grafts. The size of the pearls is controlled by the intramolecular hydrophilic-hydrophobic balance, whereas the total number of pearls in the graft copolymer depends on the length of the main chain. The results of simulations, in particular behavior of polymers of finite chain length, are rationalized on the basis of revised and extended scaling theory. Intramolecular structures in amphiphilic graft copolymers with hydrophilic side chains and hydrophobic backbone have been studied by molecular dynamics simulations. We have found that balance of repulsive and attractive intramolecular interactions may result in the pearl-necklace-type conformations. The globular ?pearls? are formed by collapsed segments of the main chain comprising multiple spacers; these pearls are stabilized against aggregation by repulsive interactions of the hydrophilic grafts. The size of the pearls is controlled by the intramolecular hydrophilic-hydrophobic balance, whereas the total number of pearls in the graft copolymer depends on the length of the main chain. The results of simulations, in particular behavior of polymers of finite chain length, are rationalized on the basis of revised and extended scaling theory.
dcterms:title
Amphiphilic Graft Copolymers in Selective Solvents: Molecular Dynamics Simulations and Scaling Theory Amphiphilic Graft Copolymers in Selective Solvents: Molecular Dynamics Simulations and Scaling Theory
skos:prefLabel
Amphiphilic Graft Copolymers in Selective Solvents: Molecular Dynamics Simulations and Scaling Theory Amphiphilic Graft Copolymers in Selective Solvents: Molecular Dynamics Simulations and Scaling Theory
skos:notation
RIV/00216208:11310/09:10000118!RIV10-GA0-11310___
n3:aktivita
n13:P n13:Z
n3:aktivity
P(GD203/05/H001), P(IAA400500703), Z(MSM0021620857)
n3:cisloPeriodika
17
n3:dodaniDat
n4:2010
n3:domaciTvurceVysledku
n5:4471474 n5:4637895 n5:9105514 n5:7786476
n3:druhVysledku
n8:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
302657
n3:idVysledku
RIV/00216208:11310/09:10000118
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Block copolymer; polyelectrolytes; pearl-necklace; polymer chains; conformation, poor solvents
n3:klicoveSlovo
n7:poor%20solvents n7:polyelectrolytes n7:pearl-necklace n7:conformation n7:polymer%20chains n7:Block%20copolymer
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[2EB32416EFE9]
n3:nazevZdroje
Macromolecules
n3:obor
n9:CD
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
6
n3:projekt
n14:IAA400500703 n14:GD203%2F05%2FH001
n3:rokUplatneniVysledku
n4:2009
n3:svazekPeriodika
42
n3:tvurceVysledku
Košovan, Peter Borisov, Oleg V Zhulina, Ekaterina B Kuldová, Jitka Procházka, Karel Limpouchová, Zuzana
n3:wos
000269635900052
n3:zamer
n18:MSM0021620857
s:issn
0024-9297
s:numberOfPages
13
n10:organizacniJednotka
11310