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Statements

Subject Item
n2:RIV%2F00216208%3A11310%2F01%3A00107042%21RIV%2F2002%2FGA0%2F113102%2FN
rdf:type
n11:Vysledek skos:Concept
dcterms:description
The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H4L forms both cis- and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1,N4-[Co(HL)]. The kinetically preferred cis-isomer is easily formed due to the strong hydrogen bond between the neighboring phosphonic acid groups. The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H4L forms both cis- and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1,N4-[Co(HL)]. The kinetically preferred cis-isomer is easily formed due to the strong hydrogen bond between the neighboring phosphonic acid groups.
dcterms:title
The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid)
skos:prefLabel
The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid) The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid)
skos:notation
RIV/00216208:11310/01:00107042!RIV/2002/GA0/113102/N
n3:strany
324;330
n3:aktivita
n13:P n13:Z
n3:aktivity
P(GA203/97/0242), P(GA203/99/0067), P(GA203/99/M037), P(VS96140), Z(MSM 113100001)
n3:cisloPeriodika
1-2
n3:dodaniDat
n9:2002
n3:domaciTvurceVysledku
n5:9417850 n5:3157962 n5:3978877 n5:3062228 n5:7161875
n3:druhVysledku
n8:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
675708
n3:idVysledku
RIV/00216208:11310/01:00107042
n3:jazykVysledku
n16:eng
n3:klicovaSlova
cis/trans-isomerism; cobalt(III) complexes; methylphosphonic acid
n3:klicoveSlovo
n4:cobalt%28III%29%20complexes n4:cis%2Ftrans-isomerism n4:methylphosphonic%20acid
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[6667FA13C678]
n3:nazevZdroje
Inorganica Chimica Acta
n3:obor
n6:CA
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n10:GA203%2F99%2FM037 n10:GA203%2F97%2F0242 n10:GA203%2F99%2F0067 n10:VS96140
n3:rokUplatneniVysledku
n9:2001
n3:svazekPeriodika
317
n3:tvurceVysledku
Rohovec, Jan Hermann, Petr Kotek, Jan Císařová, Ivana Lukeš, Ivan
n3:zamer
n14:MSM%20113100001
s:issn
0020-1693
s:numberOfPages
7
n15:organizacniJednotka
11310