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Statements

Subject Item
n2:RIV%2F00216208%3A11160%2F13%3A10145915%21RIV14-GA0-11160___
rdf:type
n12:Vysledek skos:Concept
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0040402013007898
dcterms:description
Ionic liquids with natural organic derived anions (L-lactate, L-tartrate, malonate, succinate, L-malate, pyruvate, D-glucuronate, D-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H-2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed. Ionic liquids with natural organic derived anions (L-lactate, L-tartrate, malonate, succinate, L-malate, pyruvate, D-glucuronate, D-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H-2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed.
dcterms:title
Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
skos:prefLabel
Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
skos:notation
RIV/00216208:11160/13:10145915!RIV14-GA0-11160___
n12:predkladatel
n19:orjk%3A11160
n3:aktivita
n11:I n11:P
n3:aktivity
I, P(GAP207/10/2048)
n3:cisloPeriodika
30
n3:dodaniDat
n5:2014
n3:domaciTvurceVysledku
n10:4728858
n3:druhVysledku
n15:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
63497
n3:idVysledku
RIV/00216208:11160/13:10145915
n3:jazykVysledku
n14:eng
n3:klicovaSlova
Biodegradation; Toxicity; Hydrogenation; Characterization; Synthesis; Ionic liquids
n3:klicoveSlovo
n6:Characterization n6:Toxicity n6:Hydrogenation n6:Ionic%20liquids n6:Synthesis n6:Biodegradation
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[CAFDAC6D4341]
n3:nazevZdroje
Tetrahedron
n3:obor
n16:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
11
n3:projekt
n20:GAP207%2F10%2F2048
n3:rokUplatneniVysledku
n5:2013
n3:svazekPeriodika
69
n3:tvurceVysledku
Bouquillon, Sandrine Gatard, Sylvain Gathergood, Nicholas Beadham, Ian Kuemmerer, Klaus Courty, Matthieu Špulák, Marcel Ghavre, Mukund Ferlin, Nadege Haiss, Annette Quilty, Brid
n3:wos
000321474100019
s:issn
0040-4020
s:numberOfPages
12
n13:doi
10.1016/j.tet.2013.05.054
n18:organizacniJednotka
11160