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Statements

Subject Item
n2:RIV%2F00216208%3A11160%2F12%3A10124686%21RIV13-MSM-11160___
rdf:type
n15:Vysledek skos:Concept
rdfs:seeAlso
http://www.worldscientific.com/doi/pdf/10.1142/S1088424612500800
dcterms:description
Two series of peripherally substituted azaphthalocyanines (AzaPcs) containing different transition metals (Al(III), Zn(II), Ga(III), In(III) and Fe(II)) were synthesized and studied for their photophysical properties. As confirmed by UV-vis and H-1 NMR analyses, the non-aggregation behavior was effectively induced by the applied bulky peripheral substituents which had no effect on the photophysical properties. Tuning the Q-band position was clearly achievable by using different central heavy metals which have considerable effects on the fluorescence quantum yield and singlet oxygen generation efficiency. This comparative study showed an interesting linear relationship between the former and atomic number of the central metal. The indium containing complexes exhibited the best result due to the heavy metal effect and therefore could be promoted as a potential photosensitizer in photodynamic therapy (PDT) application. Two series of peripherally substituted azaphthalocyanines (AzaPcs) containing different transition metals (Al(III), Zn(II), Ga(III), In(III) and Fe(II)) were synthesized and studied for their photophysical properties. As confirmed by UV-vis and H-1 NMR analyses, the non-aggregation behavior was effectively induced by the applied bulky peripheral substituents which had no effect on the photophysical properties. Tuning the Q-band position was clearly achievable by using different central heavy metals which have considerable effects on the fluorescence quantum yield and singlet oxygen generation efficiency. This comparative study showed an interesting linear relationship between the former and atomic number of the central metal. The indium containing complexes exhibited the best result due to the heavy metal effect and therefore could be promoted as a potential photosensitizer in photodynamic therapy (PDT) application.
dcterms:title
Heavy metal effects on physicochemical properties of non-aggregated azaphthalocyanine derivatives Heavy metal effects on physicochemical properties of non-aggregated azaphthalocyanine derivatives
skos:prefLabel
Heavy metal effects on physicochemical properties of non-aggregated azaphthalocyanine derivatives Heavy metal effects on physicochemical properties of non-aggregated azaphthalocyanine derivatives
skos:notation
RIV/00216208:11160/12:10124686!RIV13-MSM-11160___
n15:predkladatel
n16:orjk%3A11160
n3:aktivita
n4:P n4:I
n3:aktivity
I, P(GAP207/11/1200)
n3:cisloPeriodika
7-8
n3:dodaniDat
n12:2013
n3:domaciTvurceVysledku
n14:8014019 n14:2424703
n3:druhVysledku
n5:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n20:predkladatel
n3:idSjednocenehoVysledku
138760
n3:idVysledku
RIV/00216208:11160/12:10124686
n3:jazykVysledku
n18:eng
n3:klicovaSlova
fluorescence; singlet oxygen; heavy metal effect; azaphthalocyanine
n3:klicoveSlovo
n10:heavy%20metal%20effect n10:singlet%20oxygen n10:fluorescence n10:azaphthalocyanine
n3:kodStatuVydavatele
FR - Francouzská republika
n3:kontrolniKodProRIV
[1B55B875FA41]
n3:nazevZdroje
Journal of Porphyrins and Phthalocyanines
n3:obor
n19:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:projekt
n7:GAP207%2F11%2F1200
n3:rokUplatneniVysledku
n12:2012
n3:svazekPeriodika
16
n3:tvurceVysledku
Nováková, Veronika Tuhl, Ahmad Samuel, Jacob Makhseed, Saad Al-Awadi, Nouria Zimčík, Petr
n3:wos
000307022900011
s:issn
1088-4246
s:numberOfPages
9
n8:doi
10.1142/S1088424612500800
n21:organizacniJednotka
11160