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Statements

Subject Item
n2:RIV%2F00216208%3A11160%2F11%3A10118896%21RIV12-MSM-11160___
rdf:type
skos:Concept n14:Vysledek
rdfs:seeAlso
http://onlinelibrary.wiley.com/doi/10.1002/aoc.1823/pdf
dcterms:description
A series of tri- and diorganotin(IV) compounds containing potentially chelating S,N-ligand(s) (L(SN), where L(SN) is 6-phenylpyridazine-3-thiolate) were prepared and structurally characterized by multinuclear NMR spectroscopy. X-ray diffraction techniques were used for determination of the structure of compounds containing one [(L(SN))Ph(2)SnCl], two [(n-Bu)(2)Sn(L(SN))(2)] and the combination of two L(SN) and one L(CN) [(L(CN))(n-Bu)Sn(L(SN))(2)] (where L(CN) is {2-[(CH(3))(2)NCH(2)]C(6)H(4)}-) ligands. The coordination number of the tin atom varies from five to seven and is dependent on the number of chelating ligands present. The formation of the five-membered azastanna heterocycle is favored over the formation of four-membered azastannathia heterocycle in compounds containing both types of ligands. The di-n-butyl-substituted compounds are the most efficient ones in inhibition of growth of yeasts, molds and G(+) bacteria strains. A series of tri- and diorganotin(IV) compounds containing potentially chelating S,N-ligand(s) (L(SN), where L(SN) is 6-phenylpyridazine-3-thiolate) were prepared and structurally characterized by multinuclear NMR spectroscopy. X-ray diffraction techniques were used for determination of the structure of compounds containing one [(L(SN))Ph(2)SnCl], two [(n-Bu)(2)Sn(L(SN))(2)] and the combination of two L(SN) and one L(CN) [(L(CN))(n-Bu)Sn(L(SN))(2)] (where L(CN) is {2-[(CH(3))(2)NCH(2)]C(6)H(4)}-) ligands. The coordination number of the tin atom varies from five to seven and is dependent on the number of chelating ligands present. The formation of the five-membered azastanna heterocycle is favored over the formation of four-membered azastannathia heterocycle in compounds containing both types of ligands. The di-n-butyl-substituted compounds are the most efficient ones in inhibition of growth of yeasts, molds and G(+) bacteria strains.
dcterms:title
S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study
skos:prefLabel
S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study
skos:notation
RIV/00216208:11160/11:10118896!RIV12-MSM-11160___
n14:predkladatel
n15:orjk%3A11160
n4:aktivita
n13:Z n13:I n13:S n13:P
n4:aktivity
I, P(GAP207/10/0215), S, Z(MSM0021627501)
n4:cisloPeriodika
10
n4:dodaniDat
n21:2012
n4:domaciTvurceVysledku
n6:8932360
n4:druhVysledku
n8:J
n4:duvernostUdaju
n10:S
n4:entitaPredkladatele
n19:predkladatel
n4:idSjednocenehoVysledku
230098
n4:idVysledku
RIV/00216208:11160/11:10118896
n4:jazykVysledku
n20:eng
n4:klicovaSlova
antibacterial and fungicidal study; X-ray diffraction analyses; NMR spectroscopy; organotin(IV) compounds
n4:klicoveSlovo
n9:X-ray%20diffraction%20analyses n9:NMR%20spectroscopy n9:antibacterial%20and%20fungicidal%20study n9:organotin%28IV%29%20compounds
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[156399498D6B]
n4:nazevZdroje
Applied Organometallic Chemistry
n4:obor
n18:CA
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
8
n4:projekt
n22:GAP207%2F10%2F0215
n4:rokUplatneniVysledku
n21:2011
n4:svazekPeriodika
25
n4:tvurceVysledku
Růžička, Aleš Vejsová, Marcela Švec, Petr Vaňkátová, Hana Padělková, Zdeňka Česlová, Lenka Ozerianskyi, Andrii Holeček, Jaroslav
n4:wos
000295294800001
n4:zamer
n5:MSM0021627501
s:issn
0268-2605
s:numberOfPages
10
n7:doi
10.1002/aoc.1823
n11:organizacniJednotka
11160