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Statements

Subject Item
n2:RIV%2F00209805%3A_____%2F13%3A%230000429%21RIV14-GA0-00209805
rdf:type
n11:Vysledek skos:Concept
rdfs:seeAlso
http://onlinelibrary.wiley.com/doi/10.1002/elan.201300170/pdf
dcterms:description
Protein catalyzed hydrogen evolution reaction at mercury-containing electrodes controlled by constant-current chronopotentiometric stripping (CPS) is representing a new tool useful in protein research. The resulting CPS peak H is sensitive to changes in the protein structure and its amino acid composition. Besides CPS, cyclic voltammetry appears to be useful for study of poly(amino acids) as an intermediate model system between peptides and macromolecular proteins. Here we show that similarly as arginine in polyarginine and lysine in polylysine also histidine residues in polyhistidine contribute to the catalysis of hydrogen evolution under the given conditions. Peak potentials of individual poly(amino acids) are different and depend on the type of amino acid residues. Protein catalyzed hydrogen evolution reaction at mercury-containing electrodes controlled by constant-current chronopotentiometric stripping (CPS) is representing a new tool useful in protein research. The resulting CPS peak H is sensitive to changes in the protein structure and its amino acid composition. Besides CPS, cyclic voltammetry appears to be useful for study of poly(amino acids) as an intermediate model system between peptides and macromolecular proteins. Here we show that similarly as arginine in polyarginine and lysine in polylysine also histidine residues in polyhistidine contribute to the catalysis of hydrogen evolution under the given conditions. Peak potentials of individual poly(amino acids) are different and depend on the type of amino acid residues.
dcterms:title
Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes
skos:prefLabel
Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes
skos:notation
RIV/00209805:_____/13:#0000429!RIV14-GA0-00209805
n11:predkladatel
n19:ico%3A00209805
n3:aktivita
n18:I n18:P n18:Z
n3:aktivity
I, P(ED2.1.00/03.0101), P(GA13-00956S), Z(AV0Z50040702)
n3:cisloPeriodika
9
n3:dodaniDat
n6:2014
n3:domaciTvurceVysledku
n7:9991646
n3:druhVysledku
n16:J
n3:duvernostUdaju
n21:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
64404
n3:idVysledku
RIV/00209805:_____/13:#0000429
n3:jazykVysledku
n17:eng
n3:klicovaSlova
catalytic hydrogen evolution; cyclic voltammetry; constant-current chronopotentiometric stripping; mercury electrode; polyamino acids
n3:klicoveSlovo
n13:mercury%20electrode n13:catalytic%20hydrogen%20evolution n13:constant-current%20chronopotentiometric%20stripping n13:cyclic%20voltammetry n13:polyamino%20acids
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[3A32A2DC59A9]
n3:nazevZdroje
Electroanalysis
n3:obor
n20:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:projekt
n10:GA13-00956S n10:ED2.1.00%2F03.0101
n3:rokUplatneniVysledku
n6:2013
n3:svazekPeriodika
25
n3:tvurceVysledku
Paleček, Emil
n3:wos
000327590600015
n3:zamer
n14:AV0Z50040702
s:issn
1040-0397
s:numberOfPages
6
n5:doi
10.1002/elan.201300170