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Statements

Subject Item
n2:RIV%2F00025798%3A_____%2F06%3A00000226%21RIV07-GA0-00025798
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Fázové vztahy v kovy bohaté části soustavy Co-Ni-P byly studovány v zatavených, evakuovaných kamenných trubicích. V soustavě bylo identifikováno pět binárních fází: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P a pět ternárních pevných roztoku: (Co1-x, Nix)3P, ë1-(Ni1?xCox)2P (hexagonální), ë2-Co1?xNix)2P (ortorombický),(Co1-x,Nix)12P5 a (Co1-x,Nix)5P2. Kobalt má významný vliv na strukturu Ni-Co fosfidu. The metal-rich portion of the Co-Ni-P system was studied experimentally at 800 oC by means of evacuated silica glass tube technique. Five binary phases: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P and five ternary phosphides solid solutions: (Co1-x, Nix)3P, ?1-(Ni1-xCox)2P (hexagonal), ?2-Co1-xNix)2P (orthorhombic),(Co1-x,Nix)12P5 and (Co1-x,Nix)5P2 were found to be stable in the system. Cobalt has a significant influence on the structure of (Ni,Co)2P solid solutions and, therefore, cobalt contents might change the crystal structure of naturally occurring phosphides with the Ni/P = 2:1 ratio. Ni-rich, cobalt-containing phosphides with the Ni/P ratio = 3:1 and 2:1, isotypic with minerals schreibersite and barringerite, could possibly be found in meteorites. Likewise, phosphides with Ni/P ratio = 12:5 and 5:2 may possibly be found, but in close association with natural Ni-rich phosphides. The metal-rich portion of the Co-Ni-P system was studied experimentally at 800 oC by means of evacuated silica glass tube technique. Five binary phases: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P and five ternary phosphides solid solutions: (Co1-x, Nix)3P, ?1-(Ni1-xCox)2P (hexagonal), ?2-Co1-xNix)2P (orthorhombic),(Co1-x,Nix)12P5 and (Co1-x,Nix)5P2 were found to be stable in the system. Cobalt has a significant influence on the structure of (Ni,Co)2P solid solutions and, therefore, cobalt contents might change the crystal structure of naturally occurring phosphides with the Ni/P = 2:1 ratio. Ni-rich, cobalt-containing phosphides with the Ni/P ratio = 3:1 and 2:1, isotypic with minerals schreibersite and barringerite, could possibly be found in meteorites. Likewise, phosphides with Ni/P ratio = 12:5 and 5:2 may possibly be found, but in close association with natural Ni-rich phosphides.
dcterms:title
The metal-rich part of the Co-Ni-P system at 800 oC The metal-rich part of the Co-Ni-P system at 800 oC Kovem bohatá část soustavy Co-Ni-P při 800 oC.
skos:prefLabel
The metal-rich part of the Co-Ni-P system at 800 oC The metal-rich part of the Co-Ni-P system at 800 oC Kovem bohatá část soustavy Co-Ni-P při 800 oC.
skos:notation
RIV/00025798:_____/06:00000226!RIV07-GA0-00025798
n4:strany
545-550
n4:aktivita
n7:P
n4:aktivity
P(GA205/05/0459)
n4:cisloPeriodika
18
n4:dodaniDat
n12:2007
n4:domaciTvurceVysledku
n8:5535263
n4:druhVysledku
n9:J
n4:duvernostUdaju
n13:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
485052
n4:idVysledku
RIV/00025798:_____/06:00000226
n4:jazykVysledku
n17:eng
n4:klicovaSlova
phase relations, phosphides, Co, Ni, P
n4:klicoveSlovo
n5:Co n5:phosphides n5:phase%20relations n5:Ni n5:P
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[EB12D57D51E8]
n4:nazevZdroje
Europ. Journ. of Mineralogy
n4:obor
n6:DB
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
1
n4:projekt
n15:GA205%2F05%2F0459
n4:rokUplatneniVysledku
n12:2006
n4:svazekPeriodika
5
n4:tvurceVysledku
Drábek, Milan
s:issn
0935-1221
s:numberOfPages
6